Hofmann and Strauss have observed a peculiar action of the cathode rays
on the active lead sulphate separated by them. They state that the
activity diminishes with time, but is recovered by exposure of the lead
for a short time to the action of cathode rays. No such action is shown
by the active lead sulphide. This effect is due most probably to the
action of the cathode rays in causing a strong phosphorescence of the
lead sulphate and has nothing to do with the radio-activity proper of
the substance.
=23. Is thorium a radio-active element?= The similarity of the chemical
properties of actinium and thorium has led to the suggestion at
different times that the activity of thorium is not due to thorium
itself, but to the presence of a slight trace of actinium. In view of
the difference in the rate of decay of the emanations of thorium and
actinium, this position is not tenable. If the activity of thorium were
due to actinium, the two emanations, as well as the other products
obtained from these substances, should have identical rates of decay.
Since there is not the slightest evidence that the rate of decay of
activity of the various products can be altered by chemical or physical
agencies, we may conclude with confidence that whatever radio-active
substance is responsible for the activity of thorium, it certainly is
not actinium. This difference in the rate of decay of the active
products is of far more weight in deciding the question whether two
bodies contain the same radio-active constituent than differences in
chemical behaviour, for it is quite probable that the active material in
each case may exist only in minute quantity in the matter under
examination, and, under such conditions, a direct chemical examination
in the first place is of little value.
Recent work of Hofmann and Zerban and of Baskerville, however, certainly
tends to show that the element thorium is itself non-radio-active, and
that the radio-activity observed in ordinary thorium compounds is due to
the admixture with it of an unknown radio-active element. Hofmann and
Zerban[42] made a systematic examination of the radio-activity of
thorium obtained from different mineral sources. They found generally
that thorium, obtained from minerals containing a large percentage of
uranium, were more active than those obtained from minerals nearly free
from uranium. This indicates that the radio-activity observed in thorium
may possibly be due to a transformation product of uranium which is
closely allied chemically to thorium and is always separated with it. A
small quantity of thorium obtained from the mineral gadolinite was found
by Hofmann to be almost inactive, whether tested by the electric or by
the photographic method. Later Baskerville and Zerban[43] found that
thorium obtained from a Brazilian mineral was practically devoid of
activity.
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