When the emanation is removed from a radium compound by solution or
heating, the activity _measured by the_ β _rays_ falls almost to zero,
but increases in the course of a month to its original value. The curve
showing the rise of β and γ rays with time is practically identical with
the curve, Fig. 85, showing the recovery of the lost activity of radium
measured by the α rays. The explanation of this result lies in the fact
that the β and γ rays from radium only arise from the active deposit,
and that the non-separable activity of radium gives out only α rays. On
removal of the emanation, the activity of the active deposit decays
nearly to zero, and in consequence the β and γ rays almost disappear.
When the radium is allowed to stand, the emanation begins to accumulate,
and produces in turn the active deposit, which gives rise to β and γ
rays. The amount of β and γ rays (allowing for a period of retardation
of a few hours) will then increase at the same rate as the activity of
the emanation, which is continuously produced from the radium.
=216. Effect of escape of emanation.= If the radium allows some of the
emanation produced to escape into the air, the curve of recovery will be
different from that shown in Fig. 85. For example, suppose that the
radium compound allows a constant fraction α of the amount of emanation,
present in the compound at any time, to escape per second. If _n_ is the
number of emanation particles present in the compound at the time _t_,
the number of emanation particles changing in the time _dt_ is λ_ndt_,
where λ is the constant of decay of activity of the emanation. If _q_ is
the rate of production of emanation particles per second, the increase
of the number _dn_ in the time _dt_ is given by
_dn_ = _qdt_ − λ_ndt_ − α_ndt_,
or _dn_
----- = _q_ − (λ + α)_n_.
_dt_
The same equation is obtained when no emanation escapes, with the
difference that the constant λ + α is replaced by λ. When a steady state
is reached, _dn_/_dt_ is zero, and the maximum value of _n_ is equal to
_q_/(λ + α).
If no escape takes place, the maximum value of _n_ is equal to _q_/λ.
The escape of emanation will thus lower the amount of activity recovered
in the proportion λ/(λ + α). If _n₀_ is the final number of emanation
particles stored up in the compound, the integration of the above
equation gives
$$ \frac {n} {n₀} = 1 − e^{-(λ + \alpha) t} $$ .
The curve of recovery of activity is thus of the same general form as
the curve when no emanation escapes, but the constant λ is replaced by λ
+ α.
For example, if α = λ = ¹⁄₄₆₃₀₀₀, the equation of rise of activity is
given by
$$ \frac {n} {n₀} = 1 − e^{−2λ t} $$,
and, in consequence, the increase of activity to the maximum will be far
more rapid than in the case of no escape of emanation.
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