A very slight escape of emanation will thus produce large alterations
both in the final maximum and in the curve of recovery of activity.
A number of experiments have been described by Mme Curie in her _Thèse
présentée à la Faculté des Sciences de Paris_ on the effect of solution
and of heat in diminishing the activity of radium. The results obtained
are in general agreement with the above view, that 75 per cent. of the
activity of radium is due to the emanation and the excited activity it
produces. If the emanation is wholly or partly removed by solution or
heating, the activity of the radium is correspondingly diminished, but
the activity of the radium compound is spontaneously recovered owing to
the production of fresh emanation. A state of radio-active equilibrium
is reached, when the rate of production of fresh emanation balances the
rate of change in the emanation stored up in the compound. The
differences observed in the rate of recovery of radium under different
conditions were probably due to variations in the rate of escape of the
emanation.
=217.= It has been shown in section 152 that the emanation is produced
at the same rate in the solid as in the solution, and all the results
obtained point to the conclusion that the emanation is produced from
radium at a constant rate, which is independent of physical conditions.
Radium, like thorium, shows a non-separable activity of 25 per cent. of
the maximum activity, and consisting entirely of α rays. The β and γ
rays arise only from the active deposit. The emanation itself (section
156) gives out only α rays. These results thus admit of the explanation
given in the case of thorium (section 136). The radium atoms break up at
a constant rate with the emission of α particles. The residue of the
radium atom becomes the atom of the emanation. This in turn is unstable
and breaks up with the expulsion of an α particle. The emanation is half
transformed in four days. We have seen that this emanation gives rise to
an active deposit. The results obtained up to this stage are shown
diagrammatically below.
α _particle_ α _particle_
/ /
/ /
RADIUM ATOM ——> ATOM OF EMANATION ——> ATOM OF ACTIVE DEPOSIT
=218. Analysis of the active deposit from radium.= We have seen in
chapter VIII that the excited activity produced on bodies, by the action
of the radium emanation, is due to a thin film of active matter
deposited on the surface of bodies. This active deposit is a product of
the decomposition of the radium emanation, and is not due to any action
of the radiations on the surface of the matter.
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