The curves showing the variation of the excited activity with time are
very complicated, depending not only upon the time of exposure in the
presence of the emanation, but also upon the type of radiation used for
measurement. The greater portion of the activity of this deposit dies
away in the course of 24 hours, but a very small fraction still remains,
which then changes very slowly.
It will be shown in this chapter that at least six successive
transformations occur in the active deposit. The matter initially
produced from the emanation is called radium A, and the succeeding
products B, C, D, E, F. The equations expressing the quantity of A, B,
C,...... present at any time are very complicated, but the comparison of
theory with experiment may be much simplified by temporarily
disregarding some unimportant terms: for example, the products A, B, C
are transformed at a very rapid rate compared with D. The activity due
to D + E + F is, in most cases, negligible compared with that of A or C,
being usually less than ¹⁄₁₀₀₀₀₀ of the initial activity observed for A
or C. The analysis of the active deposit of radium may thus be
conveniently divided into two stages:
(1) Analysis of the deposit of rapid change, which is mainly
composed of radium A, B, and C;
(2) Analysis of the deposit of slow change, which is composed of
radium D, E, and F.
=219. Analysis of the deposit of rapid change.= In the experiments
described below, a radium solution was placed in a closed glass vessel.
The emanation then collected in the air space above the solution. The
rod, to be made active, was introduced through an opening in the stopper
and exposed in the presence of the emanation for a definite interval. If
the decay was to be measured by the α rays, the rod was made the central
electrode in a cylindrical vessel such as is shown in Fig. 18. A
saturating voltage was applied, and the current between the cylinders
measured by an electrometer. If a very active rod is to be tested, a
sensitive galvanometer can be employed, but, in such a case, a large
voltage is required to produce saturation. A slow current of dust-free
air was continuously circulated through the cylinder, in order to remove
any emanation that may have adhered to the rod. For experiments on the β
and γ rays, it was found advisable to use an electroscope, such as is
shown in Fig. 12, instead of an electrometer. For measurements with the
γ rays, the active rod was placed under the electroscope, and before
entering the vessel the rays passed through a sheet of metal of
sufficient thickness to absorb all the α rays. For measurements with the
γ rays, the electroscope was placed on a lead plate 0·6 cms. thick, and
the active rod placed under the lead plate. The α and β rays were
completely stopped by the lead, and the discharge in the electroscope
was then due to the γ rays alone. The electroscope is very advantageous
for measurements of this character, and accurate observations can be
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