The product B only escapes from the body for a short time after removal. This is a strong indication that its apparent volatility is connected with the presence of the rapidly changing product radium A. Since A breaks up with an expulsion of an α particle, some of the residual atoms constituting radium B may acquire sufficient velocity to escape into the gas, and are then transferred by diffusion to the walls of the vessel. Miss Brooks observed that the activity was not concentrated on the negative electrode in an electric field but was diffused uniformly over the walls of the vessel. This observation is of importance in considering the explanation of the anomalous effects exhibited by the active deposit of radium, which will be discussed in the following section. =228. Effect of the first rapid change.= We have seen that the law of decay of activity, measured by the β or γ rays, can be explained very satisfactorily if the first 3-minute change is disregarded. The full theoretical examination of the question given in sections 197 and 198 and the curves of Figs. 72 and 73 show, however, that the presence of the first change should exercise an effect of sufficient magnitude to be detected in measurements of the activity due to the succeeding changes. The question is of great interest, for it involves the important theoretical point whether the substances A and B are produced independently of one another, or whether A is the parent of B. In the latter case, the matter A which is present changes into B, and, in consequence, the amount of B present after A is transformed should be somewhat greater than if B were produced independently. Since the change of A is fairly rapid, the effect should be most marked in the early part of the curve. In order to examine this point experimentally, the curve of rise of activity, measured by the β rays, was determined immediately after the introduction of a large quantity of the radium emanation into a closed vessel. The curve of decay of activity on a body for a long exposure after removal of the emanation, and the rise of activity after the introduction of the emanation, are in all cases complementary to one another. While, however, it is difficult to measure with certainty whether the activity has fallen in a given time, for example, from 100 to 99 or 98·5, it is easy to be sure whether the corresponding rise of activity in the converse experiment is 1 or 1·5 per cent. of the final amount. Fig. 92, curve I, shows the rise of activity (measured by the β rays) obtained for an interval of 20 minutes after the introduction of the emanation. The ordinates represent the percentage amount of the final activity regained at any time. Curve III shows the theoretical curve obtained on the assumption that A is a parent of B. This curve is calculated from equation (9) discussed in section 198, and λ₁, λ₂, λ₃ are the values previously found.