=24.= If elements heavier than uranium exist, it is probable that they
will be radio-active. The extreme delicacy of radio-activity as a means
of chemical analysis would enable such elements to be recognized even if
present in infinitesimal quantities. It is probable that considerably
more than the three or four radio-elements at present recognized exist
in minute quantity, and that the number at present known will be
augmented in the future. In the first stage of the search, a purely
chemical examination is of little value, for it is not probable that the
new element should exist in sufficient quantity to be detected by
chemical or spectroscopic analysis. The main criteria of importance are
the existence or absence of distinctive radiations or emanations, and
the permanence of the radio-activity. The discovery of a radio-active
emanation with a rate of decay different from those already known would
afford strong evidence that a new radio-active body was present. The
presence of either thorium or radium in matter can very readily be
detected by observing the rate of decay of the emanations given out by
them. When once the existence of a new radio-element has been inferred
by an examination of its radio-active properties, chemical methods of
separation can be devised, the radiating or emanating property being
used as a guide in qualitative and quantitative analysis.
Footnote 1:
Niewenglowski, _C. R._ 122, p. 385, 1896.
Footnote 2:
Becquerel, _C. R._ 122, p. 559, 1896.
Footnote 3:
Troost, _C. R._ 122, p. 564, 1896.
Footnote 4:
Arnold, _Annal. d. Phys._ 61, p. 316, 1897.
Footnote 5:
Le Bon, _C. R._ 122, pp. 188, 233, 386, 462, 1896.
Footnote 6:
Becquerel, _C. R._ 122, pp. 420, 501, 559, 689, 762, 1086, 1896.
Footnote 7:
Mme Curie, _Thèse présentée à la Faculté des Sciences de Paris_, 1903.
Footnote 8:
_Nature_, 56, 1897; _Phil. Mag._ 43, p. 418, 1897; 45, p. 277, 1898.
Footnote 9:
Rutherford, _Phil. Mag._ Jan. 1899.
Footnote 10:
_Ibid._
Footnote 11:
Le Bon, _C. R._ 130, p. 891, 1900.
Footnote 12:
Lenard, _Annal. d. Phys._ 1, p. 498; 3, p. 298, 1900.
Footnote 13:
Schmidt, _Annal. d. Phys._ 65, p. 141, 1898.
Footnote 14:
Mme Curie, _C. R._ 126, p. 1101, 1898.
Footnote 15:
Owens, _Phil. Mag._ Oct. 1899.
Footnote 16:
Rutherford, _Phil. Mag._ Jan. 1900.
Footnote 17:
M. and Mme Curie and G. Bemont, _C. R._ 127, p. 1215, 1898.
Footnote 18:
Giesel, _Phys. Zeit._ 3, No. 24, p. 578, 1902.
Footnote 19:
Giesel, _Annal. d. Phys._ 69, p. 91, 1890. _Ber. d. D. Chem. Ges._ p.
3608, 1902.
Footnote 20:
Demarçay, _C. R._ 127, p. 1218, 1898; 129, p. 716, 1899; 131, p. 258,
1900.
Footnote 21:
Runge, _Astrophys. Journal_, p. 1, 1900. _Annal. d. Phys._ No. 10, p.
407, 1903.
Footnote 22:
Exner and Haschek, _Wien. Ber._ July 4, 1901.
Footnote 23:
Crookes, _Proc. Roy. Soc._ 72, p. 295, 1904.
Footnote 24:
Runge and Precht, _Annal. d. Phys._ XIV. 2, p. 418, 1904.
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