=232. Effect of temperature on the activity.= A platinum plate, made
active in the manner described, was exposed to varying temperatures in
an electric furnace, and the activity tested at atmospheric temperature
after exposure. Four minutes’ exposure in the furnace, at first at 430°
C., and afterwards at 800° C., had little, if any, effect on the
activity. After four minutes at about 1000° C. the activity decreased
about 20 per cent., and a further exposure of eight minutes at a
temperature of about 1050° C. almost completely removed the α ray
activity. On the other hand, the β ray activity, when measured
immediately after removal, was not altered by the heating, but exposure
to a still higher temperature caused it to decrease. These results show
that the active matter consists of two kinds. The part which emits β
rays is not volatile at 1000° C., but the other part, which emits α
rays, is almost completely volatilized at that temperature.
It was found, however, that the β ray activity after heating to about
1000° was not permanent, but decayed according to an exponential law
with the time, the activity decreasing to half value in about 4·5 days.
From the recovery curve of the β ray activity already considered, it was
to be expected that the activity would decay to half value in six days.
This difference in the periods is possibly due to an effect of the high
temperature in altering the rate of decay of radium E. The period of six
days is more probably correct. The results obtained on the rise and
decay of the β rays, taken together, show:—
(1) That the product giving β rays is supplied at a constant rate
from some parent matter of very slow rate of change.
(2) That this parent matter is volatilized at or below 1000° C., and
the β ray product is left behind. Since the parent matter is
removed, the product immediately begins to lose its activity at its
characteristic rate, viz. the activity falls to half value in about
six days.
=233. Separation of the constituents by means of a bismuth plate.= The
active matter of slow decay was obtained in solution by introducing
dilute sulphuric acid into a glass tube in which the emanation from 30
milligrams of radium bromide had been stored for a month. The solution
showed strong activity and gave out both α and β rays, the latter, as in
other cases, being present in an unusually large proportion.
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