=231. Variation of the β ray activity.= The residual activity consists
of both α and β rays, the latter being present initially in an unusually
large proportion. The proportion of α to β rays from the platinum plate,
one month after removal, was at the most one-fiftieth of that from a
thin film of radium bromide in radio-active equilibrium. Unlike the α
ray activity, the activity measured by the β rays remains constant after
the active deposit is about one month old, and, in consequence, the
proportion of α to β rays steadily increases with the time. The
experiments showed that the intensity of the β rays did not vary much,
if at all, over a further period of eighteen months. The want of
proportionality between the α and β rays shows that the two types of
rays arise from different products. This conclusion is confirmed by
experiments, to be described later, which show that the products giving
rise to α and β rays can be temporarily separated from one another by
physical and chemical means.
[Illustration: Fig. 94.]
If observations of the active deposit are begun shortly after its
formation, it is found that the activity, measured by the β rays, is
small at first, but increases with the time, reaching a practical
maximum about 40 days later. Experiments were made on a platinum plate,
which was exposed for 3·75 days in a vessel containing the radium
emanation. The observations of the β ray activity began 24 hours after
removal. The results are shown in Fig. 94, where the time was measured
from the middle of the time of exposure to the emanation. Similar
results were obtained for a negatively charged wire exposed to the
emanation. The curve, if produced back to the origin, is seen to be very
similar to the recovery curves of Ur X, and other active products, and
can be expressed by the equation
$$ \frac {I_t} {I₀} = 1 − e^{–λt} $$,
where _I₀_ is the maximum activity. The activity reaches half its final
value in about six days, and the value of λ is equal to ·115 (day)⁻¹. We
have shown in section 203 that a rising curve of this character
indicates that the β ray activity arises from a product which is
supplied at a constant rate from a primary source. Before discussing in
detail the explanation of these curves, showing the rise with time of
the α and β ray activity, further experimental results will be
considered.
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