Radium D = product in _new radio-lead_, no rays. Half transformed in
40 years.
Radium E gives out β rays, separated with bismuth, iridium and
platinum. Half transformed in 6 days.
Radium F = product in _polonium_ and _radio-tellurium_. Gives out
only α rays. Half transformed in 143 days.
=242. Temporary activity of inactive matter separated from radio-active
substances.= We have seen in the last section that the platinum metals
and bismuth acquire temporary activity by their admixture with a
solution of radio-lead, and that these effects are very satisfactorily
explained on the view that some of the products of change of radio-lead
are removed with the inactive substances. Very similar effects have been
observed by Pegram and von Lerch (section 186), when inactive substances
were added to solutions of thorium and of the active deposit of thorium.
These results, too, are almost certainly due to the removal of one or
more of the products of thorium with the inactive matter. Examples of
this character may readily be multiplied, and some of the more
interesting and important of these will be briefly discussed later.
There have been two general points of view regarding the character of
this activity which is temporarily acquired by inactive matter. Some
people have supposed that the inactive molecules of the substance, mixed
with the solution, acquire by “radio-active induction” temporary
activity, the underlying idea being that the close admixture of an
inactive and an active substance has communicated the property of
radiating to some of the molecules of the former. According to the
disintegration theory of radio-activity, on the other hand, the
temporary activity of originally inactive matter is not due to any
alteration of the inactive substance itself, but to an admixture with it
of one or more of the numerous radio-active products. The idea of
“radio-active induction” has no definite experimental evidence in
support of it, while there is much indirect evidence against it.
We shall now consider how these facts are interpreted according to the
disintegration theory. In a specimen of old radium, for example, there
are present, besides radium itself, the seven successive products which
arise from it. Each of these differs in chemical and physical properties
from the others. If now, for example, a bismuth rod is introduced into
the solution, one or more of these products are deposited on the
bismuth. This action is most probably electrolytic in nature, and will
depend upon the electro-chemical behaviour of the bismuth compared with
that of the products in solution. An electro-negative substance will
tend to remove the product or products which are strongly
electro-positive. This point of view serves to explain why different
metals are made active to different degrees, depending upon their
position in the electro-chemical series.
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