It seems probable that the activity communicated to inactive matter by
precipitation from an active solution occurs only during the
precipitation. The correctness of this view could readily be tested by
observing whether the time that the inactive substance is present in
solution has any effect on the magnitude of the activity imparted to it.
When it is remembered that in pitchblende there are present the
radio-elements uranium, thorium, radium and actinium and their numerous
family of products, it is not surprising that many of the inactive
substances separated from it may show very considerable activity due to
the mixture of products which may be removed with them. In carrying out
experiments on the separation of radium from pitchblende, M. and Mme
Curie observed that the separation of the active substance is fairly
complete if the stage of purification is not far advanced. Copper,
antimony and arsenic can be separated only slightly active, but other
substances like lead and iron always show activity. When the stage of
precipitation is more advanced, every substance separated from the
active solution shows activity.
One of the earliest observations in this direction was made by Debierne,
who found that barium could be made active by solution with actinium.
The active barium removed from the actinium still preserved its activity
after chemical treatment, and, in this way, barium chloride was obtained
whose activity was 6000 times that of uranium. Although the activity of
the barium chloride could be concentrated in the same way as the
activity of radiferous barium chloride, it did not show any of the
spectroscopic lines of radium, and could not have been due to the
admixture of that element with the barium. The activity of the barium
was not permanent, and Debierne states that the activity fell to about
one-third of its value in three months. It seems probable that the
precipitated barium carried down with it the product actinium X, and
also some of the actinium itself, and that the decay observed was due to
the transformation of actinium X. It is interesting to note that barium
is capable of removing a large number of products of the different
radio-elements. This effect is probably connected with its position in
the electro-chemical series, for barium is highly electro-positive.
Giesel showed in 1900 that bismuth could be made active by placing it in
a radium solution, and considered that polonium was in reality bismuth
made active by the process of induction. In later experiments, he found
that the bismuth plate gave out only α rays, and that the activity of
the bismuth could not be ascribed to radium, since no β rays were
present. We have seen that this activity of the bismuth is due to the
product radium F deposited on its surface.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account