It has long been known that, if air saturated with water-vapour be
suddenly expanded, a cloud of small globules of water is formed. These
drops are formed round the dust particles present in the gas, which act
as nuclei for the condensation of water around them. The experiments of
R. von Helmholtz and Richarz[65] had shown that chemical reactions, for
example the combustion of flames, taking place in the neighbourhood,
affected the condensation of a steam-jet. Lenard showed that a similar
action was produced when ultra-violet light fell on a negatively charged
zinc surface placed near the steam-jet. These results suggested that the
presence of electric charges in the gas facilitated condensation.
A very complete study of the conditions of condensation of water on
nuclei has been made by C. T. R. Wilson[66]. An apparatus was
constructed which allowed a very sudden expansion of the air over a wide
range of pressure. The amount of condensation was observed in a small
glass vessel. A beam of light was passed into the apparatus which
allowed the drops formed to be readily observed by the eye.
Preliminary small expansions caused a condensation of the water round
the dust nuclei present in the air. These dust nuclei were removed by
allowing the drops to settle. After a number of successive small
expansions, the air was completely freed from dust, so that no
condensation was produced.
Let _v₁_ = initial volume of the gas in the vessel, _v₂_ = volume after
expansion.
If _v₂_/_v₁_ < 1·25 no condensation is produced in dust-free air. If
however _v₂_/_v₁_ > 1·25 and < 1·38, a few drops appear. This number is
roughly constant until _v₂_/_v₁_ = 1·38, when the number suddenly
increases and a very dense cloud of fine drops is produced.
If the radiation from an X ray tube or a radio-active substance is now
passed into the condensation vessel, a new series of phenomena is
observed. As before, if _v₂_/_v₁_ < 1·25 no drops are formed, but if
_v₂_/_v₁_ = 1·25 there is a sudden production of a cloud. The water
drops of which this cloud is formed are finer and more numerous the
greater the intensity of the rays. The point at which condensation
begins is very marked, and a slight variation of the amount of expansion
causes either a dense cloud or no cloud at all.
Public-domain text, read in full here on John Shaqi.
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