This difference in behaviour of the positive and negative ions was
investigated in detail by C. T. R. Wilson[68] in the following way. X
rays were made to pass in a narrow beam on either side of a plate _AB_
(Fig. 7) dividing the condensation vessel into two equal parts. The
opposite poles of a battery of cells were connected with two parallel
plates _C_ and _D_, placed symmetrically with regard to _A_. The middle
point of the battery and the plate _A_ were connected with earth. If the
plate _C_ is positively charged, the ions in the space _CA_ at a short
distance from _A_ are all negative in sign. Those to the right are all
positive. It was found that condensation occurred only for the negative
ions in _AC_ when _v₂_/_v₁_ = 1·25 but did not occur in _AD_ for the
positive ions until _v₂_/_v₁_ = 1·31.
Thus the negative acts more readily than the positive ion as a centre of
condensation. The greater effect of the negative ion in causing
condensation has been suggested as an explanation of the positive charge
always observed in the upper atmosphere. The negative ions under certain
conditions become centres for the formation of small drops of water and
are removed to the earth by the action of gravity, while the positive
ions remain suspended.
With the apparatus described above, it has been shown that the positive
and negative ions are equal in number. If the expansion is large enough
to ensure condensation on both ions, the drops formed on the right and
left of the vessel in Fig. 7 are equal in number and fall at the same
rate, _i.e._ are equal in size.
Since the ions are produced in equal numbers from a gas electrically
neutral, this experiment shows that the charges on positive and negative
ions are equal in value but opposite in sign.
=36. Charge carried by an ion.= For a known sudden expansion of a gas
saturated with water vapour, the amount of water precipitated on the
ions can be calculated readily. The size of the drops can be determined
by observing the rate at which the cloud settles under the action of
gravity. From Stokes’ equation, the terminal velocity _u_ of a small
sphere of radius _r_ and density _d_ falling through a gas of which the
coefficient of viscosity is μ is given by
2 _dgr²_
_u_ = --------
9 μ
where _g_ is the acceleration due to gravity. The radius of the drop and
consequently the weight of water in each drop can thus be determined.
Since the total weight of water precipitated is known, the number of
drops present is obtained at once.
This method has been used by J. J. Thomson[69] to determine the charge
carried by an ion. If the expansion exceeds the value 1·31, both
positive and negative ions become centres of condensation. From the rate
of fall it can be shown that approximately the drops are all of the same
size.
Public-domain text, read in full here on John Shaqi.
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