_dp_ _nXeK_
---- = 0 and _u_ = ----,
_dx_ _p_
Let _N_ be the number of molecules in a cubic centimetre of gas at the
pressure _P_ and at the temperature 15° C., for which the values of _u_
and _K_ have been determined. Then _N_/_P_ may be substituted for
_n_/_p_, and, since _P_ at atmospheric pressure is 10⁶,
3 × 10⁸_u₁_
_Ne_ = ---------- electrostatic units,
_K_
where _u₁_ is the velocity for 1 volt (_i.e._ ¹⁄₃₀₀ E. S. unit) per cm.
It is known that one absolute electromagnetic unit of electricity in
passing through water liberates 1·23 c.c. of hydrogen at a temperature
of 15° C. and standard pressure. The number of atoms in this volume is
2·46_N_, and, if _e´_ is the charge on the hydrogen atom in the
electrolysis of water,
2·46 _Ne´_ = 3 × 10¹⁰ E. S. units,
_Ne´_ = 1·22 × 10¹⁰ E. S. units.
_e_ _u₁_
Thus --- = 2·46 × 10⁻² ----
_e´_ _K_
For example, substituting the values of _u₁_ and _K_ determined in
moist air for the positive ion,
_e_ 2·46 1·37
--- = ----- × ----- = 1·04.
_e´_ 100 ·032
Values of this ratio, not very different from unity, are obtained for
the positive and negative ions of the gases hydrogen, oxygen, and carbon
dioxide. Taking into consideration the uncertainty in the experimental
values of _u₁_ and _K_, these results indicate that the _charge carried
by an ion in all gases is the same and is equal to that carried by the
hydrogen ion in the electrolysis of liquids_.
=39. Number of the ions.= We have seen that, from experimental data,
Townsend has found that _N_, the number of molecules present in 1 c.c.
of gas at 15° C. and standard pressure, is given by
_Ne_ = 1·22 × 10¹⁰.
Now _e_, the charge on an ion, is equal to 3·4 × 10⁻¹⁰ E. S. units;
thus _N_ = 3·6 × 10⁻¹⁹.
If _I_ is the saturation current through a gas, and _q_ the total rate
of production of ions in the gas,
_I_
_q_ = --- .
_e_
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