The measurement of radioactivity must be accomplished indirectly, so use is made of the physical, chemical, and electrical effects of radiation on materials. One commonly used effect is that of ionization. Alpha and beta particles ionize gases through which they pass, thereby making the gases electrically conductive. A family of counters uses this principle: the ionization chamber, the proportional counter, and the Geiger-Müller counter. Certain crystals, sodium iodide being an excellent example, emit flashes of visible light when struck by ionizing radiation. These crystals are used in scintillation counters. Ionization Chambers One of a pair of electrodes is a wire located centrally within a cylinder. The other electrode is the wall of the chamber. Radiation ionizes the gas within the chamber, permitting the passage of current between the electrodes. The thickness of a window in the chamber wall determines the type of radiation it can measure. Only gamma rays will pass through a heavy metal wall, glass windows will admit all gammas and most betas, and plastic (Mylar) windows are necessary to admit alpha particles. Counters of this type, when properly calibrated, will measure the total amount of radiation received by the body of the wearer. Proportional Counters This is a type of ionization chamber in which the intensity of the electrical pulse it produces is proportional to the energy of the incoming particle. This makes it possible to record alpha particles and discriminate against gamma rays. Geiger-Müller Counters These have been widely used and are versatile in their applications. The potential difference between the electrodes in the Geiger-Müller tube (similar to an ionization chamber) is high. A single alpha or beta particle ionizes some of the gas within the chamber. In turn these ions strike other gas molecules producing secondary ionization. The result is an “avalanche” or high-intensity pulse of electricity passing between the electrodes. These pulses can be counted electrically and recorded on a meter at rates up to several thousand per minute. Scintillation Counters Since the development of the photoelectric tube and the photomultiplier tube (a combination of photoelectric cell and amplifier), the scintillation counter has become the most popular instrument for most purposes described in this booklet. The flash of light produced when an individual ionizing particle or ray strikes a sodium-iodide crystal is noted by a photoelectric cell. The intensity of the flash is a measure of the energy of the radiation, so the voltage of the output of the photomultiplier tube is a measure of the wavelength of the original gamma ray. The scintillation counter can observe up to a million counts per minute and discriminate sharply between gamma rays of different energies. With proper windows it can be used for alpha or beta counts as well. Solid State Counters