Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
The paper making fibres are shown to fall into a scheme of
classification based on chemical constitution, and consisting of the
four groups: (a) Cotton [flax, hemp, rhea], (b) wood celluloses,
(c) esparto, straw, and (d) lignocelluloses. Papers being exposed to
the natural disintegrating agencies, more especially oxygen, water (and
hydrolysing agents generally), and micro-organisms, the relative
resistance of the above groups of raw materials is discussed as an
important condition of value. The indirect influence of the ordinary
sizing and 'filling' materials is discussed. The paper-making quality of
the fibrous raw materials is also discussed, not merely from the point
of view of the form and dimensions of the ultimate fibres, but their
capacity for 'colloidal hydration.' This is complementary to the action
of rosin, i.e. resin acids, in the engine-sizing of papers; and the
proof of the potency of this factor is seen in the superior effects
obtained in sizing jointly with solutions of cellulose and, more
particularly, viscose and rosin. Wurster's much-cited monograph of the
subject of rosin-sizing ['Le Collage des Papiers,' Bull. Mulhouse, 1878]
neglects to take into consideration the contribution of the cellulose
hydrates to the total and complex sizing effect, and hence gives a
partial view only of the function of the resin acids.
In further illustration of fundamental principles various developments
in the textile industries are discussed, e.g. the bleaching of jute,
cotton, and flax, and special developments in the spinning of rhea and
flax.
The concluding lecture deals with later progress in the industrial
applications of cellulose derivatives, chiefly the sulphocarbonate
(viscose); the nitrates, in their applications to explosives, on the one
hand, and the spinning of artificial fibres (lustra-cellulose), on the
other; and the cellulose acetates.
~La Viscose et le Viscoide.~
C. H. BARDY (Bull. Soc. d'Enc. Ind. Nationale, 1900, March).
This is a report presented to the Committee of Economic Arts of the
above Society, dealing with the industrial progress in products obtained
by means of the sulphocarbonate of cellulose (viscose).
The following developments are noted:
_Engine-sized Papers._--The viscose, by coating the fibres with
regenerated cellulose hydrate, adds very much to the tensile strength of
papers. Increase of 40-60 p.ct. is attainable by addition of cellulose
in this form from 1-4 p.ct. on the weight of the paper.
_Viscoid._--Solid aggregates are formed by incorporating viscose with
mineral matters, hydrocarbons, &c. Products are cast or moulded into
convenient forms, and, after purification and sufficient ageing, are
available for various structural uses.
Public-domain text, read in full here on John Shaqi.
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