Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
_Paint._--The viscose is used as a vehicle for pigments, the mixture
being used either as a paint or for coating papers with fine surfaces,
such as required in the reproduction of photo-blocks. In these
applications the extraordinary viscosity of the product conditions the
economic use of the cellulose in competition with oils, on the one hand,
and organic colloids, such as gelatine, casein, &c., on the other.
By suitable alteration of the formula for making the paint a product is
obtained which has an extraordinary power of removing paint from old
painted surfaces. The product has been officially adopted by the French
Admiralty, and receives extensive application in removing the paint from
ships.
_Films._--Films are produced from the viscose itself in various ways.
Plane or flat by solidifying the viscose on glass surfaces, removing the
by-products and rolling the films. The film is also produced by
applying the viscose on textile fabrics, drying down, and fixing on a
stenter machine, then washing away the alkaline by-products from the
fixed film. A large number of industrial effects are obtained by
suitably varying the mixtures applied.
_Cellulose-indiarubber._--The viscose, in its concentrated form, can be
incorporated with rubber-hydrocarbon mixtures, and these mixtures can be
used both as water-proofing films, as applied to textiles, or can be
solidified into the class of goods known as 'mechanicals.' The cellulose
not only cheapens the mixture, but produces new technical effects.
_Spinning._--The viscose is spun by special methods, patented by C. H.
Stearn. As produced in thread form, the diameters are approximately
those of natural silk. In commercial form it is a multiple thread (of 15
or more units) at from 50-200 deniers on the silk counts. It is a thread
of high lustre, and more nearly approaches the normal cellulose in
chemical properties than any of the other artificial silks. It can also
be spun in threads of very much larger diameter, which can be used as a
substitute for horsehair, for carbonising for incandescent electric
lamps, &c.
_Cellulose Esters._--These are conveniently made from cellulose,
regenerated from the solution as sulphocarbonate. The tetracetate is
made from this product on the industrial scale. Nitrates are
conveniently made by treatment with the ordinary mixed acids. For fuller
details the original report may be consulted.
VISKOS.
R. W. STREHLENERT (Svensk Kemisk Tidskrift, Stockholm, 1900, p. 185).
A report on the industrial development of viscose, covering essentially
the same ground as the above.
~Ueber die Viscose.~
B. M. MARGOSCHES (Reprint from Zeitschrift fuer die gesammte
Textil-Industrie, 1900-01, Nos. 14-20).[11]
~Report of Committee on the Deterioration of Paper.~
(Soc. of Arts, 1898.)
Public-domain text, read in full here on John Shaqi.
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