Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
In bleaching processes there has been no radical change of system on the
large scale since the introduction of the 'Mather' kier in 1885, and the
associated change from lime and ash boiling to the caustic soda
circulating boil with reduced volume of lye, which this mechanical
device rendered practicable. It is outside the scope of this work to
follow up this branch of technology in any detail, and we cannot discuss
the evolution of systems on variations of detail where no essential
principle is involved. But we have to notice a very recent development
which has only just begun its industrial career, and which does give
effect to a principle of treatment not previously applied. This is
tersely stated by its originator, William Mather,[13] in the
expression, 'it is more economical to make liquids pass through cloth
than to make cloth pass through liquids.' The starting point of this
development is the invention of a complete self-contained machine in
which a rolled batch of cloth can receive a succession of chemical
treatments, with accessory washings--the solutions, or wash waters,
being circulated through the cloth. The essential fact on which this
system is based is that a perfect liquid circulation can be maintained
from selvedge to selvedge through the folds of a tightly rolled batch of
cloth. Such circulation is therefore quite independent of the diameter
of the batch. If we consider a cloth under chemical treatment with
solutions, it is clear that the reactions and interchanges of soluble
matters within the cloth, within the twisted elements of the yarn, and
in the last grade of distribution within the actual ultimate fibres, are
subject to capillary transmission, and osmotic exchange. There is a
mixture of these molecular effects, with the circulation in mass,
sweeping both faces of the cloth. It is obvious that for the mass effect
a relatively very small volume of circulating liquid is necessary to
maintain uniform conditions of action. In the actual disposition of the
machine the rolled batch of cloth nearly fills the cylindrical space of
what we may call the reaction chamber, and the circulation of the liquid
is maintained by a circulating pump and a differential pressure in the
horizontal plane across and through the folds of the batch. This is in
the meantime kept in slow revolution. For a full description of these
mechanical details the reader is referred to the original patent
specifications [Engl. Pat. 23,400, 23,401; 1900, W. Mather]. If we again
consider the principles involved, they are very much as set forth in
our original work (pp. 288-291). Boiling processes in which a
relatively large volume of liquid is used are wasteful of steam, the
active agent is unnecessarily diluted or used in superfluous quantity,
and the soluble by-products, being continually removed as formed, cannot
so effectively contribute by secondary actions to the chemical work. The
new mechanical appliance enables us to further reduce the volume of
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