Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
liquid required in the alkaline-hydrolytic treatment of vegetable
textiles, and where advantageous to bring the treatment down (or up) to
a process of steaming with the active agent dissolved in a minimum
proportion of water relative to the cloth. This concentration of effect
is of importance in flax cloth, and especially linen treatment, where
the peculiarly resistant cutocelluloses have to be attacked and a
considerable proportion of waxy by-products to be removed. These points
are the basis of the special process of Cross and Parkes [Engl. Pat.
25,076/ 99] for steaming flax (and cotton) goods with an emulsion
containing, in addition to the special hydrolysing agent--caustic
soda--mixtures of soap with 'mineral' or other oils, the presence of
which effectually aids the removal of the by-products in question.
A complete system on these lines is now working on the industrial scale
in the Belfast district. The results are not merely economical in
largely reducing the number of alkaline boiling treatments required on
the old plan of pan or 'pot' boiling, but are visible in the strength
and finish of the linens so treated.
For cotton bleaching the costs may be put down at a fraction of those of
the Irish linen bleach. The economical advantages of the new system are
obviously less in relation to the lesser total costs. But there are
other points which have come into more prominent influence. The
mechanical wear and tear on the cloth is considerable in the ordinary
process, more especially in the mangle-washes. As a result the
adjustment of warp and weft is more or less disturbed. These defects are
absent from a system which operates on the cloth in a fixed position.
But as we are mainly concerned with the purely chemical factors we
cannot pretend to deal with textile questions. We have to notice the
remaining element of chemical economy as it involves a fundamental
principle. The practice of washing residues or products of reaction free
from reagents and soluble by-products involves a well-known mathematical
law, under which the rate of purification is a function rather of the
_number_ of successive changes of washing liquid than of the volume of
the latter. The ordinary practice of textile washings entirely ignores
this principle, and the consumption of water in consequence may reach
many thousand times the economic minimum. With supplies of water often
in indefinite excess of requirements, even in this most wasteful method,
bleachers are in no need to consider the question of consumption. But
leaving aside particular and local considerations of advantage the fact
is that the new system gives control of the practice of washing,
enabling the operator to adapt an important element of the daily routine
to a fundamental principle which has been almost universally ignored.
Public-domain text, read in full here on John Shaqi.
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