Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
_Gabriel's_ method of heating with a glycerin solution of alkaline
hydrate is a combination of 'Hoenig' and 'Lange.' An extended
investigation showed as in the case of the latter that the
celluloses themselves are more or less profoundly attacked by the
treatment--further that the celluloses isolated from lignocelluloses and
other complex raw materials are much 'less pure' than those obtained by
the Lange process. Thus, notably in regard to furfural yielding
constituents, the latter yield 1-2 p.ct. furfural, whereas _specimens of
'jute cellulose'_ obtained by the Gabriel process were found to yield _9
to 13 p.ct. furfural_.
_Cross and Bevan._--Chlorination process yielded in the hands of the
authors results confirming the figures given in 'Cellulose' for yield of
cellulose. Investigation of the products for yield of furfural, gave 9
p.ct. of this aldehyde showing the presence of celluloses, other than
the normal type.
_Conclusions._--The subjoined table gives the mean numerical results for
yield of end-product or 'cellulose' by the various methods. In the case
of the 'celluloses' the results are those of the further action of the
several processes on the end-product of a previous process.
| Methods
| F. Schulze | Weende | Lange | Gabriel | Cross
| | | | | and Bevan
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Wood cellulose | 98.51 | 91.52 | 48.22 | 55.93 | --
Filter paper cellulose | 99.62 | 95.63 | 78.17 | 79.77 | --
Swedish filter paper | 96.58 | -- | 84.76 | -- | --
Ordinary filter paper | 98.17 | 93.39 | 86.58 | -- | --
Cotton ('wool') | 98.38 | 89.98 | 63.96 | 67.88 | --
Jute | -- | -- | 57.93 | 71.64 | 75.27
Purified wood | -- | -- |{49.27 | -- | --
| | |{46.56 | |
Raw wood | 47.60 | -- |{40.82 | -- | --
| | |{38.87 | |
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The final conclusion drawn from the results is that none of the
processes fulfil the requirements of an ideal method. Those which may
be carried out in a reasonably short time are deficient in two
directions: (1) they yield a 'cellulose' containing more or less
oxycellulose; (2) the celluloses themselves are attacked under the
conditions of treatment, and the end product or cellulose merely
represents a particular and at the same time variable equilibrium, as
between the resistance of the cellulose and the attack of the reagents
employed; this attack being by no means confined to the non-cellulose
constituents. Schulze's method appears to give the nearest approximation
to the 'actual cellulose' of the raw material.
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