Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
(p. 15) ~Reactions of cellulose with iodine.~--In a recent paper, F.
Mylius deals with the reaction of starch and cellulose with iodine,
pointing out that the blue colouration depends upon the presence of
water and iodides. In absence of the latter, and therefore in presence
of compounds which destroy or absorb hydriodic acid--e.g. iodic
acid--there results a _brown_ addition product. The products in question
have the characteristics of _solid solutions_ of the halogen. (Berl.
Ber. 1895, 390.)
(24) ~Mercerisation~--Notwithstanding the enormous recent developments in
the industrial application of the mercerising reaction, there have been
no noteworthy contributions to the theoretical aspects of the subject.
The following abstract gives an outline of the scope of an important
technical work on the subject.
DIE MERCERISATION DER BAUMWOLLE.
PAUL GARDNER (Berlin: 1898. J. Springer).
~THE MERCERISATION OF COTTON.~
This monograph of some 150 pages is chiefly devoted to the patent
literature of the subject. The chemical and physical modifications of
the cotton substance under the action of strong alkaline lye, were set
forth by Mercer in 1844-5, and there has resulted from subsequent
investigations but little increase in our knowledge of the fundamental
facts. The treatment was industrially developed by Mercer in certain
directions, chiefly (1) for preparing webs of cloth required to stand
considerable strain, and (2) for producing crepon effects by local or
topical action of the alkali. But the results achieved awakened but a
transitory interest, and the matter passed into oblivion; so much so,
indeed, that a German patent [No. 30,966] was granted in 1884 to the
Messrs. Depouilly for crepon effects due to the differential shrinkage
of fabrics under mercerisation, by processes and treatments long
previously described by Mercer. Such effects have had a considerable
vogue in recent years, but it was not until the discovery of the
lustreing effect resulting from the association of the mercerising
actions with the condition of strain or tension of the yarn or fabric
that the industry in 'mercerised' goods was started on the lines which
have led to the present colossal development. The merit of this
discovery is now generally recognised as belonging to Thomas and Prevost
of Crefeld, notwithstanding that priority of patent right belongs to the
English technologist, H. A. Lowe.
Public-domain text, read in full here on John Shaqi.
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