Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
The more important general indications of the above results are--(1) The
mercerisation action commences with a lye of 10 deg.B., and increases with
increased strength of the lye up to a maximum at 35 deg.B. There is,
however, a relatively slight increase of action with the increase of
caustic soda from 30-40 deg.B. (2) For optimum action the temperature should
not exceed 15-20 deg.C. (3) The duration of action is of proportionately
less influence as the concentration of the lye increases. As the maximum
effect is attained the action becomes practically instantaneous, the
only condition affecting it being that of penetration--i.e. actual
contact of cellulose and alkali.
(d) The question as to whether the process of 'mercerisation' involves
chemical as well as physical effects is briefly discussed. The author is
of opinion that, as the degree of lustre obtained varies with the
different varieties of cotton, the differentiation is occasioned by
differences in chemical constitution of these various cottons. The
influence of the chemical factors is also emphasised by the increased
dyeing capacity of the mercerised goods, which effect, moreover, is
independent of those conditions of strain or tension under mercerisation
which determine lustre. It is found in effect that with a varied range
of dye stuffs a given shade is produced with from 10 to 30 p.ct. less
colouring matter than is required for the ordinary, i.e. unmercerised,
goods.
In reference to the constants of strength and elasticity, Buntrock gives
the following results of observations upon a 40^{5} twofold yarn, five
threads of 50 cm. length being taken for each test(Prometheus, 1897, p.
690): (a) the original yarn broke under a load of 1440 grms.; (b)
after mercerisation without tension the load required was 2420 grms.;
(c) after mercerisation under strain, 1950 grms. Mercerisation,
therefore, increases the strength of the yarn from 30 to 66 p.ct., the
increase being lessened proportionately to the strain accompanying
mercerisation. _Elasticity_, as measured by the extension under the
breaking load, remains about the same in yarns mercerised under strain,
but when allowed to shrink under mercerisation there is an increase of
30-40 p.ct. over the original.
The _change of form_ sustained by the individual fibres has been studied
by H. Lange [Farberzeitung, 1898, 197-198], whose microphotographs of
the cotton fibres, both in length and cross-section, are reproduced. In
general terms, the change is from the flattened riband of the original
fibre to a cylindrical tube with much diminished and rounded central
canal. The effect of strain under mercerisation is chiefly seen in the
contour of the surface, which is smooth, and the obliteration at
intervals of the canal. Hence the increased transparency and more
complete reflection of the light from the surface, and the consequent
approximation to the optical properties of the silk fibre.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account