Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
1 mol celloxin: {2 mol. cellulose on 6 hours' heating
{3 mol. cellulose on 3 hours' heating
with a ratio H : O = 1 : 9 and 1 : 8.7 respectively: they yielded 7
p.ct. furfural.
B. _By action of bromine in presence of water and_ CaCO_{3} _upon
cotton_.--Yield, (air-dry) 85 p.ct. Empirical composition
C_{12}H_{20}O_{11} = C_{6}H_{10}O_{5}.C_{6}H_{10}O_{6}: yielded furfural
1.7 p.ct.
C. _Cotton and nitric acid at_ 100 deg., two and a half hours (Cross and
Bevan).--Yield, 70 p.ct. Composition
4 C_{6}H_{10}O_{5}.C_{6}H_{8}O_{6}
yielded furfural 2.3 p.ct.
D. _Cotton and nitric acid at_ 100 deg. (four hours).--A more highly
oxidised product resulted, viz. 3 C_{6}H_{10}O_{5}.C_{6}H_{8}O_{6}:
yielded furfural 3.2 p.ct.
_By-products of oxidation._--The liquors from B were found to contain
saccharic acid: the acid from C and B contained a dibasic acid which
appeared to be tartaric acid.
The isolation of (1) isosaccharinic and (2) dioxybutyric acid from the
products of digestion of the oxycelluloses with lime-milk at 100 deg. was
effected by the separation of their respective calcium salts, (1) by
direct crystallisation, (2) by precipitation alcohol after separation of
the former.
CELLULOSES, HYDRO- AND OXYCELLULOSES, AND CELLULOSE ESTERS.
L. VIGNON (Bull. Soc. Chim., 1901 [3], 25, 130).
(a) _Oxycelluloses from cotton, hemp, flax, and ramie._--The
comparative oxidation of these celluloses, by treatment with HClO_{3}
at 100 deg., gave remarkably uniform results, as shown by the following
numbers, showing extreme variations: yields, 68-70 p.ct.; hydrazine
reaction, N fixed 1.58-1.69; fixation of basic colouring matters
(relative numbers), saffranine, 100-200, methylene blue, 100-106. The
only points of difference noted were (1) hemp is somewhat more resistant
to the acid oxidation; (2) the cotton oxycellulose shows a somewhat
higher (25 p.ct.) cupric reduction.
(b) _'Saccharification' of cellulose, cellulose hydrates, and
hydrocellulose._--The products were digested with dilute hydrochloric
acid six hours at 100 deg., and the cupric reduction of the soluble products
determined and calculated to dextrose.
100 grms. of gave reducing products equal to Dextrose
Purified cotton 3.29
" Hydrocellulose 9.70
Cotton mercerised (NaOH 30 deg. B.) 4.39
Cotton mercerised (NaOH 40 deg. B.) 3.51
Cellulose reprecipitated from cuprammonium 4.39
Oxycellulose 14.70
Starch 98.6
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