Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
L. VIGNON.
~Resume of investigations (1898-1900) of Oxycellulose, published as a
brochure~ (Rey, Lyon, 1900).
(a) A typical oxycellulose prepared from cotton cellulose by the
action of HClO_{3} (HCl + KClO_{3}) in dilute solution at 100 deg. for one
hour gave the following numbers:
C H O
Elementary composition 43.55 6.03 50.42
Oxycellulose Original cellulose
Analysis by Lange's method
Soluble in KOH (at 180 deg.) 87.6 12.0
Insoluble in KOH (at 180 deg.) 12.4 88.0
Oxycellulose Original cellulose
Heat of combustion 4124-4133 4190-4224
Heat evolved in contact with 50 times wt.}
normal KOH per 100 grms. } 1.3 cal. 0.74 cal.
Oxycellulose Cellulose
Absorption of colouring } Saffranine 0.7 0.0
matters at 100 deg. per 100 grms. } Methylene blue 0.6 0.2
(b) _Yield of furfural from cellulose, oxy- and
hydro-cellulose._--From the hydrocelluloses variously prepared the
author obtains 0.8 p.ct. furfural; from bleached cotton 1.8 p.ct.; and
from the oxycelluloses variously prepared 2.0-3.5 p.ct. The 'furfuroid'
is relatively more soluble in alkaline solutions (KOH) in the cold. The
insoluble residue is a normal cellulose.
(c) _Nitrates of cellulose, oxy- and hydro-cellulose._--Treated with
the usual acid mixture (H_{2}SO_{4} 3 p., HNO_{3} 1 p.) under conditions
for maximum action, the resulting esters showed uniformly a fixation of
11.0 NO_{2} groups per unit mol. of C_{24}. The oxycellulose nitrate
was treated directly with dilute solution of potassium hydrate in the
cold. From the products of decomposition the author obtained the osazone
of hydroxypyruvic acid [Will, Ber. 24, 400].
(d) _Osazones of the oxycelluloses._--Oxycelluloses prepared by
various methods are found to fix varying proportions of phenylhydrazine
(residue), viz. from 3.4-8.5 p.ct. of the cellulose derivative reacting,
corresponding with, i.e. calculated from, the nitrogen determined in the
products (0.87-2.2 p.ct.). The reaction is assumed to be that of osazone
formation.
The author has also established a relation between the phenylhydrazine
fixed and the furfural which the substance yields on boiling with
condensing acids. This is illustrated by the subjoined series of
numbers:
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