Phenylhydrazine Furfural Fixed p.ct. formed p.ct. Cotton (bleached) 1.73 1.60 Oxycellulose (HClO_{3}) 7.94 2.09 " (HClO) 3.37 1.79 " (CrO_{3}) (1) 7.03 3.00 " (CrO_{3}) (2) 7.71 3.09 " (CrO_{3}) (3) 8.48 3.50 (e) _Constitution of cellulose and oxycellulose._--The results of these investigations are generalised as regards cellulose (C_6) by the constitutional formula CH--CH_{2} / | | (CHOH)_{3} O | \ | | CH--O . The oxycelluloses contain the characteristic group COH / (CHOH)_{3} \ CH--CO \ / O in union with varying proportions of residual cellulose. QUANTITATIVE SEPARATION OF CELLULOSE-LIKE CARBOHYDRATES IN VEGETABLE SUBSTANCES. WILHELM HOFFMEISTER (Landw. Versuchs-Stat., 1897, 48, 401-411). To separate the hemicelluloses, celluloses, and the constituents of lignin without essential change, the substance, after being freed from fat, is extracted with dilute hydrochloric acid and ammonia, and the residue frequently agitated for a day or two with 5-6 p.ct. caustic soda solution. It is then diluted, the extract poured off, neutralised with hydrochloric acid, treated with sufficient alcohol, and the hemicellulose filtered, dried, and weighed. The residue from the soda extract is washed on a filter with hot water, and extracted with Schweizer's reagent. When the final residue (lignin) is subjected to prolonged extraction with boiling dilute ammonia (a suitable apparatus is described, with sketch) until the ammonia is no longer coloured, a residue is obtained which mostly dissolves in Schweizer's reagent, and on repeating the process the residue is found to consist largely of mineral matter. The dissolved cellulose-like substances often contain considerable amounts of pentosanes. According to the nature of the substance, the extraction with ammonia may take weeks, or months, or even longer; the ammonia extracts of hard woods (as lignum vitae) and of cork are dark brown, and give an odour of vanilla when evaporated down. The residues, which are insoluble in water, but redissolve in ammonia, have the properties of humic acids. Other vegetable substances, when extracted, yielded, besides humic acids, a compound, C_{6}H_{7}O_{2}, soluble in alcohol and chloroform, but insoluble in water, ether, and benzene; preparations from different sources melted between 200 deg. and 210 deg.. FOOTNOTES: [4] The original paper is reproduced with slight alterations.