Researches on Cellulose, 1895-1900Cross, C. F. (Charles Frederick)
Science
Researches on Cellulose, 1895-1900
Cross, C. F. (Charles Frederick)
Cellulose
The _pectocelluloses_ have not been the subject of systematic chemical
investigation, but the researches of Gilson ('La Cristallisation de la
Cellulose et la Composition Chimique de la Membrane Cellulaire
Vegetale,' 'La Revue,' 'La Cellule,' i. ix.) are an important
contribution to the natural history of cellulose, especially in relation
to the 'pectic' constituents of the parenchymatous celluloses.
Indirectly also the researches of Tollens on the 'pectins' have
contributed to the subject in correcting some of the views which have
had a text-book currency for a long period. These are dealt with on p.
151. The results establish that the pectins are rather the soluble
hydrated form of cellulosic aggregates in which acid groups may be
represented; but such groups are not to be regarded as essentially
characteristic of this class of compounds.
~Furfural-yielding Substances~ (Furfuroids).--This group of plant products
has been, by later investigations, more definitely and exclusively
connected with the celluloses--i.e. with the more permanent of plant
tissues. From the characteristic property of yielding furfural, which
they have in common with the pentoses, they have been assumed to be the
anhydrides of these C_{5} sugars or pentosanes; but the direct evidence
for this assumption has been shown to be wanting. In regard to their
origin the indirect evidences which have accumulated all point to their
formation in the plant from hexoses. Of special interest, in its
bearings on this point, is the direct transformation of levulose into
furfural derivatives, which takes place under the action of condensing
agents. The most characteristic is that produced by the action of
anhydrous hydrobromic acid in presence of ether [Fenton], yielding a
brommethyl furfural
C_{6}H_{12}O_{6} - 4H_{2}O + HBr = C_{5}H_{3}.O_{2}.CH_{2}Br
with a Br atom in the methyl group. These researches of Fenton's appear
to us to have the most obvious and direct bearings upon the genetic
relationships of the plant furfuroids and not only _per se_. To give
them their full significance we must recall the later researches of
Brown and Morris, which establish that cane sugar is a primary or direct
product of assimilation, and that starch, which had been assumed to be a
species of universal _matiere premiere_, is probably rather a general
reserve for the elaborating work of the plant. If now the aldose groups
tend to pass over into the starch form, representing a temporary
overflow product of the assimilating energy, it would appear that the
ketose or levulose groups are preferentially used up in the elaboration
of the permanent tissue. We must also take into consideration the
researches of Lobry de Bruyn showing the labile functions of the typical
CO group in both aldoses and hexoses, whence we may conclude that in the
plant-cell the transition from dextrose to levulose is a very simple and
often occurring process.
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