Rocks and Their OriginsCole, Grenville A. J. (Grenville Arthur James)
Science
Rocks and Their Origins
Cole, Grenville A. J. (Grenville Arthur James)
Rocks
A certain amount of magnesium carbonate is present in the skeletons
of some marine organisms. This has been shown both by Forchammer and
Walther[911]. A foraminifer, _Nubecularia novorossica_, has been found
with 26 per cent. of magnesium carbonate, and a serpula with 7·64
per cent.; alcyonarian corals contain up to 9·32 per cent., while
calcareous algæ, such as Lithothamnium and Halimeda, contain about 12
per cent.[12]. The magnesium salt is not, however, here combined with
calcium carbonate to form the mineral dolomite; none the less it is
clear that such organisms introduce magnesium in appreciable quantities
into the constitution of marine limestones.
Marine limestones are very commonly "dolomitised." Dolomite, the joint
carbonate, CaMg(CO_{3})_{2}, contains 54·35 per cent. of calcium
carbonate and 45·65 per cent. of magnesium carbonate, or carbon dioxide
47·8, lime 30·4, and magnesia 21·8. Its specific gravity is 2·85.
The occurrence of dolomite in intimate association with calcite has
been proved by E. W. Skeats[13] in the case of modern coral-reefs,
and the secondary deposition of the mineral has been made clear. The
skeletons of the corals themselves may now consist of dolomite, while
calcite has crystallised in their interstices, or remains as part of
the original infilling of mud. The presence of dolomite in reefs has,
of course, long been known, having been observed by J. D. Dana in 1849,
and it has been realised that, by prolonged alteration, masses of
_Dolomite Rock_ become built up[14].
Commonly, the process produces a _Dolomitic Limestone_, in which
calcium carbonate is still in excess of the 54 per cent. which is
present in the mineral dolomite.
The alteration of the original limestone is, however, sufficiently
profound. The ready crystallisation of dolomite as rhombohedra destroys
the organic structure, and traces of corals or molluscan shells
disappear from great thicknesses of rock. It is uncertain whether the
process of dolomitisation proceeds most rapidly in the evaporating
waters of the lagoons, or, as Pfaff believes, at considerable depths,
where the pressure may reach 100 atmospheres. Magnesium carbonate, as
we shall note later, may be removed from dolomite in solution under
pressure at a greater rate than calcium carbonate. If this occurs in
sea-water, it would seem to militate against the production of dolomite
in the lower levels of a reef.
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