Rocks and Their OriginsCole, Grenville A. J. (Grenville Arthur James)
Science
Rocks and Their Origins
Cole, Grenville A. J. (Grenville Arthur James)
Rocks
From what we have said, it now seems probable that the great majority
of dolomitic limestones owe their magnesium to substitution from
without. Direct precipitation of dolomite has, however, been invoked
to account for several cases of Permian age, such as the Magnesian
Limestone of the county of Durham. Near Sunderland, this rock is
greatly modified, containing ball-like and other concretions,
associated with frequent cavities. Traces of the original bedding
remain, running through the concretions, and marine fossils are
abundant. Conybeare and Phillips, so far back as 1822, stated that the
nodules were devoid of magnesia, though formed in a magnesian rock. In
spite of this, these objects long appeared as dolomite in collections.
E. J. Garwood[17] showed conclusively that they resulted from the
concentration of calcium carbonate in a concretionary form. The process
whereby a dolomite may thus revert towards the ordinary limestone
condition, with removal of magnesium in most cases, has been styled
"dedolomitisation." Water containing calcium sulphate after passing
through a dolomite is found to carry magnesium sulphate by a chemical
exchange. Skeats[18], moreover, points out that, under a pressure of
five atmospheres the magnesium carbonate of dolomite becomes more
soluble than the calcium carbonate in fresh water containing carbon
dioxide. The ordinary relations are thus reversed under pressure, and a
cause of dedolomitisation may be indicated.
Under the influence of contact-action from igneous rocks, dolomite may
separate into calcium carbonate, magnesium oxide, and carbon dioxide.
The magnesium oxide takes up water and yields the flaky colourless
mineral brucite. Where silica is present, either as an impurity in the
dolomite, or introduced from an invading siliceous magma, magnesium
and calcium silicates may be built up[19]. Olivine thus arises, and,
on becoming hydrated and passing into serpentine, stains the rock
in various shades of green. The calcium carbonate crystallises as a
ground of granular calcite, and the whole mass becomes a handsome
_Ophicalcite_, or serpentinous marble. The famous rock of Connemara,
used in polished slabs, has arisen through contact with intrusive
diorite.
Dolomitic limestones are liable to decay rapidly in towns, owing to
the formation of magnesium sulphate, which, as shown above, is even
more soluble in water than is the accompanying calcium sulphate. In the
country, the crystals of dolomite resist ordinary weathering by the
carbon dioxide of the rain-water better than those of calcite; and the
rock thus becomes loosened through the loss of one constituent, and
crumbles into a dolomite sand[20]. Compact dolomites, however, have
furnished some excellent building-stones for country use, since here
the more resisting mineral forms the bulk of the rock.
Public-domain text, read in full here on John Shaqi.
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