Rocks and Their OriginsCole, Grenville A. J. (Grenville Arthur James)
Science
Rocks and Their Origins
Cole, Grenville A. J. (Grenville Arthur James)
Rocks
The nodular flint has collected round the sponge, while the sponge
itself has often disappeared. G. J. Hinde[21] has shown how readily
the spicules of siliceous sponges go into solution. Even at the bottom
of existing seas they become rounded at the ends, while their canals
become enlarged. In some fossil instances, they are replaced by
calcite. W. J. Sollas[22], emphasising this point, remarks that "it may
be taken as an almost invariable rule that the replacement of organic
silica by calcite is always accompanied by a subsequent deposition
of the silica in some form or other." This subsequent deposition is
frequently at the expense of calcite in some other part of the rock.
The solid flint is a replacement of the limestone in which it occurs.
The pocket-lens will often show traces of sponge-spicules, as dull
little rods, in the translucent substance of a flint. But the
microscope shows that the mass of the flint has the structure of the
limestone in which it lies. The foraminifera and other small structural
features of the original rock are perfectly preserved in chalcedonic
(that is, minutely crystalline) silica. Larger fossils, such as thick
molluscan shells and the tests of sea-urchins, may escape alteration,
while the chalk mud, the original ooze, with which they are infilled
has become completely silicified. This explains the internal moulds
of fossils in brown oxidised flint that are found in gravel-pits on
the surface of the Chalk, and also the tubular hollows, representing
stems of crinoids, that often occur in flint from the Carboniferous
Limestone. In the latter case, the fossil remained calcareous while
the ground became silicified, and the fossil was removed by subsequent
solution.
Where great thicknesses of strata, as may happen in the Carboniferous
Limestone, have become thus silicified, it may be presumed that
siliceous skeletons were unusually abundant in the mass. But, as
L. Cayeux[23] observes, such skeletons may be in one case entirely
removed, and in another represented by massive flints; in yet
another case, the silica may remain disseminated through the rock.
The irregularity of its segregation is shown by the growth of flints
in branching or hook-like forms, running from one bed to another in a
limestone.
Oolitic limestones and the skeletons of corals, both having been
originally made of aragonite, are often replaced by flint, forming
conclusive instances, appreciable by the naked eye, of the secondary
origin of this form of silica. Traces of diatoms are comparatively
rare, though they probably contributed to the silicification of the
freshwater Calcaire de la Brie of the Paris basin. Radiolaria, however,
have now been well recognised as flint-formers, even in dark "cherts"
of Silurian age. Radiolarian cherts have been taken as an indication
that the beds in which they occur were formed in oceanic depths.
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