Salt and the salt industryCalvert, Albert Frederick
History
Salt and the salt industry
Calvert, Albert Frederick
Salt industry and trade; Salt industry and trade -- England -- Cheshire
Rock-salt is rarely found in an absolutely pure anhydrous state, in
which it is colourless and perfectly transparent. In most rock-salt
mines such specimens are regarded as curiosities, but in the deposits
of Nevada and of Wieliezka, in Hungary (where the salt, containing
100 per cent. NaCl, is the purest in the world), large masses of
quite transparent salt are encountered. The white opaque mass which
the ordinary person is accustomed to think of as rock-salt, is the
purified product of commerce. The colour of sea-water is affected by
its percentage of salt, the colour changing from blue to green as the
quantity of salt decreases; but sea-salt is generally white, although
not transparent owing to the presence of minute particles of water,
air, etc., in its intercrystalline spaces. But rock-salt is never more
than whitish inclining to grey, and, as a general rule, it is coloured
by earth or mineral impurities. The Salt Range in the Panjab yields
a substance that varies from pink to red, according to the different
quantities of iron present as impurities. That found at Marston, in
Cheshire, varies from yellow to red and brownish-red in colour. Small
blocks of transparent salt of a deep sapphire blue are occasionally
found in the Wieliezka mines. The colour disappears on heating, and
when the salt is ground to powder. It is attributed by some chemists
to the presence of subchloride of sodium, by others to the presence of
thin cavities having parallel surfaces with gas inclusions.
Common salt, which is classed as “sweet” to distinguish it from the
bitter-tasting salts of magnesium, has a peculiar saline taste which
gains in pungency with refinement, and in its pure state is odourless.
In solution, the smallest quantity perceptible to the taste is about 15
grains to the litre, roughly, 68 grains to the gallon.
Common salt is highly soluble in cold water, and rather more so in hot
water, but while it dissolves slightly in alcohol, neither ether nor
oil has any effect upon it. One hundred parts of distilled water at
60° F. (15·5° C.) will dissolve 35·9 parts of chemically pure NaCl. A
saturated solution of common salt, therefore, contains 26·42 per cent.
NaCl. The increase of solubility of NaCl in proportion to the rise in
temperature, calculated by Gay Lussac and Poggiale, is particularly
marked between 100 deg. and 110 deg., when boiling point is passed,
the increase amounting to ·74 parts of 10 deg., as compared with an
increase of one 1·09 parts between freezing and boiling points. In a
double solution of NaCl and some other more soluble salt, as sodium
or magnesium sulphate or magnesium chloride, the solubility of sodium
chloride is very greatly reduced.
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