Salt and the salt industryCalvert, Albert Frederick
History
Salt and the salt industry
Calvert, Albert Frederick
Salt industry and trade; Salt industry and trade -- England -- Cheshire
Common salt is a crystalline substance which crystallizes in the
Isometric, Monometric, or Tesseral system. That is to say, each crystal
has three equal perpendicular planes of symmetry and six equal diagonal
planes of symmetry. The crystals generally form cubes having six
rectangular and equilateral faces. When these form on the surface of
brine the sides often collapse, giving the distinctive “hopper-shaped”
forms. More rarely the crystals form in octahedra, having eight
equal, equilateral triangular faces, or in long needles under certain
modifying conditions.
The hollow quadrangular pyramidal form with an irregular inner
surface arranged in steps, which manufactured salt generally takes,
is the result of continuous depositions of crystals from a constantly
saturated solution of brine during a considerable period, being
superimposed layer after layer upon each other.
In his exhaustive explanation of these phenomena, given in his
_Principles of Chemistry_, Mendeléeff says: “If a solution of sodium
chloride be slowly heated from above, where the evaporation takes
place, the upper layer will become saturated before the lower and
cooler layers, and therefore crystallization will begin on the surface,
and the crystals first formed will float--having also dried from
above--on the surface until they become quite soaked. Being heavier
than the solution the crystals are partially immersed in it, and the
following crystallization, also proceeding on the surface, will only
form crystals by the side of the original crystals. A funnel is formed
in this manner. It will be borne on the surface like a boat (if the
liquid be quiescent) because it will grow more from the upper edges.
We can thus understand this, at first sight, strange funnel-form of
crystallized salt. To explain why the crystallization under the above
conditions begins at the surface and not at the lower edges, it must
be mentioned that the specific gravity of a crystal of sodium chloride
is 2·16, and that a solution saturated at 25° contains 26·7 per cent.
of salt and has a specific gravity 1·2004 at 25°; at 15° a saturated
solution contains 26·5 per cent. of salt and has a specific gravity
1·203 at 15°. Hence, a solution saturated at a higher temperature
is specifically lighter, notwithstanding the greater amount of salt
it contains. With many substances, surface crystallization cannot
take place, because their solubility increases more rapidly with the
temperature than their specific gravity decreases. In this case the
saturated solution will always be in the lower layers, where also the
crystallization will take place.”
Public-domain text, read in full here on John Shaqi.
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