When radiant energy reaches a surface, only a certain part of it is
absorbed; the rest is either reflected, just as light rays are
reflected, or else passes right through it. The absorptivity, α, of a
substance tells us what percentage of radiant energy it will absorb. A
perfect absorber, or _black body_, would absorb all the radiant energy
that reached it. If such an ideal substance existed (which it doesn’t)
we would say it had an α of 1. The actual absorptivities of real
substances are indicated by numbers between 0 and 1: The α of black
velvet cloth, for example, is about 0.97; that of a polished silver
mirror is about 0.08 for solar radiation (absorptivity for most polished
metals for room temperature radiation is even lower).
We measure emissivity, ε, in very much the same way. A hypothetical
black body would emit all the energy it possibly could and have an ε of
1; the emissivities of real substances are indicated by numbers between
0 and 1. For any given frequency (or color) of light, a substance’s
absorptivity and emissivity are equal; however, the total spectrum of
frequencies of the energy absorbed is usually different from that of the
energy emitted.
The ratio between emissivity and absorptivity, α/ε, is very important,
as we shall see later. If this ratio is greater than 1, it means that a
substance absorbs heat faster than it emits it, and thus tends to become
warmer. If the ratio is less than 1, the reverse is true—the surface
emits radiant energy at a faster rate than it absorbs it, and tends to
become cooler.
How We Measure the Radiation of Heat
This is one of the fundamental relationships of modern physics:
_Q__body = ε_A_σ_T_⁴.
It was discovered experimentally by Josef Stefan in 1879, and verified
theoretically by Ludwig Boltzmann; it is known as the _Stefan-Boltzmann
Law_. This formula tells us the amount of radiant energy, Q_body, that
will be emitted by a body having the surface area _A_ when it is at the
temperature _T_. Temperature, here, is measured in degrees Rankine (°R),
or Fahrenheit temperature above absolute zero (to calculate degrees
Rankine, add 460 to the temperature in degrees Fahrenheit). The
expression ε_A_ is used to show that only a certain fraction of the
energy that would leave a perfect black body of area _A_ will actually
leave a real body of the same size; the size of this fraction is
determined by the body’s emissivity. The symbol σ is a quantity we call
the _Stefan-Boltzmann constant_.
Public-domain text, read in full here on John Shaqi.
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