Education; Priestley, Joseph, 1733-1804; Science -- Study and teaching
"In this case also, though I did not give sufficient attention to
the circumstance at that time, the flame of the candle, besides
being larger, burned with more splendour and heat than in that
species of nitrous air; and a piece of red-hot wood sparkled in it,
exactly like paper dipped in a solution of nitre, and it consumed
very fast--an experiment which I had never thought of trying with
nitrous air." [7]
Priestley obtained the same sort of air from red lead, but, as he says
himself, he remained in ignorance of the properties of this new kind of
air for seven months, or until March 1775, when he found that the new
air behaved with "nitrous gas" in the same way as the dephlogisticated
part of common air does; [8] but that, instead of being diminished to
four-fifths, it almost completely vanished, and, therefore, showed
itself to be "between five and six times as good as the best common air
I have ever met with." [9] As this new air thus appeared to be
completely free from phlogiston, Priestley called it "dephlogisticated
air."
What was the nature of this air? Priestley found that the same kind of
air was to be obtained by moistening with the spirit of nitre (which he
terms nitrous acid) any kind of earth that is free from phlogiston, and
applying heat; and consequently he says: "There remained no doubt on my
mind but that the atmospherical air, or the thing that we breathe,
consists of the nitrous acid and earth, with so much phlogiston as is
necessary to its elasticity, and likewise so much more as is required
to bring it from its state of perfect purity to the mean condition in
which we find it." [10]
Priestley's view, in fact, is that atmospheric air is a kind of
saltpetre, in which the potash is replaced by some unknown earth.
And in speculating on the manner in which saltpetre is formed,
he enunciates the hypothesis, "that nitre is, formed by a real
_decomposition of the air itself_, the _bases_ that are presented to
it having, in such circumstances, a nearer affinity with the spirit
of nitre than that kind of earth with which it is united in the
atmosphere." [11]
It would have been hard for the most ingenious person to have wandered
farther from the truth than Priestley does in this hypothesis; and,
though Lavoisier undoubtedly treated Priestley very ill, and pretended
to have discovered dephlogisticated air, or oxygen, as he called it,
independently, we can almost forgive him when we reflect how different
were the ideas which the great French chemist attached to the body
which Priestley discovered.
They are like two navigators of whom the first sees a new country, but
takes clouds for mountains and mirage for lowlands; while the second
determines its length and breadth, and lays down on a chart its exact
place, so that, thenceforth, it serves as a guide to his successors,
and becomes a secure outpost whence new explorations may be pushed.
Public-domain text, read in full here on John Shaqi.
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