Science from an Easy ChairLankester, E. Ray (Edwin Ray), Sir
History
Science from an Easy Chair
Lankester, E. Ray (Edwin Ray), Sir
Natural history; Science
Fifty years ago people were very fond of talking about “ozone,” and the
word is popularly used nowadays to signify a mysterious attribute of the
air of the sea-coast or moorland without its real significance being
generally understood. When Sir Oliver Lodge the other day warned people
against hurting their nasal passages by sniffing up an unduly strong
dose of ozone produced by a special ozone-making apparatus, I am
inclined to think that most people who read what he said wondered what
“ozone” might be.
In the eighteenth century it was noticed that the sparks from a
frictional electrical machine are accompanied by a peculiar pungent
smell in the air. Many years after that, namely in 1840, the great
chemical experimenter, Schönbein, the friend and correspondent of
Faraday and discoverer of gun-cotton, found that the smell in question
is produced by a special gas, which is formed in the air when electric
discharges take place. He found that this gas was a powerful
oxydiser—would, in fact, oxydise iodide of potassium so as to set free
iodine—and thus its presence could be detected by means of paper slips
coated with a mixture of starch and iodide of potassium. When they were
exposed in air which contained even minute traces of this strange gas
they became purple-blue, owing to the liberation of iodine and the
formation of its well-known blue combination with the starch. Schönbein
found that in breezy, fresh places his test-papers turned blue, and
concluded from that (confirmed by other evidence) that this smelling
gas, to which he gave the name ozone—which simply means “the smelling
stuff”—is present in good, ordinary atmospheric air, as well as in
artificially “electrified” air. It is destroyed when such air is heated
above the boiling-point of water, and seems to be, as it were, “taken
out” of the air by all sorts of dead organic matter, so that it is not
present in the air of large cities. I remember that when I was a boy we
used to test the air for ozone with Schönbein’s papers (I am aware that
their colour change is not absolute proof of the presence of ozone, as
other oxydising gases might, if present, act in the same way), and we
used to find more ozone when a south-west wind was blowing than in a
north-easter!
Public-domain text, read in full here on John Shaqi.
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