Science from an Easy ChairLankester, E. Ray (Edwin Ray), Sir
History
Science from an Easy Chair
Lankester, E. Ray (Edwin Ray), Sir
Natural history; Science
Schönbein wrote sixty papers on ozone—but its real nature was made out
by others who succeeded him, chiefly by Andrews, of Belfast, and Tait,
of Edinburgh. It turns out that ozone is a condensed form of the
elemental gas oxygen—squeezed, as it were, and literally “intensified,”
so that three measures of oxygen gas become only two of ozone. It very
readily changes back again—two measures of ozone expanding to form
three of oxygen. It is produced by the action of an electric discharge
upon oxygen gas driven over the discharge and in greatest quantity when
that kind of gently-buzzing electric spark which is called “the silent
discharge” is used. It can be produced in quantity by passing
atmospheric air, or better, pure dry oxygen gas through a glass tube in
which such a silent discharge is made to take place. As much as
seventeen parts in a hundred of the gas can be thus converted into
“ozone,” and some twenty years ago two French chemists succeeded in
getting even a larger proportion, and by submitting it to a tremendous
pressure at a temperature of 100 degrees below the freezing-point of
water, they obtained pure ozone as a transparent liquid. It was of a
dark indigo-blue colour, and somewhat dangerous and explosive when the
pressure under which it had formed was removed. Ordinary oxygen gas has
since then been also liquefied in the laboratory: it is of a paler blue
colour.
The “smell” which old writers had noticed and Schönbein had named was
thus actually obtained as a distinct blue liquid. It is this which,
though present only in minute quantities, gives special oxydising
activity to fresh air. When pure, or present even to the small extent of
4 per cent. in air, ozone is a destructive agent, a sort of
extra-quality oxygen of triple instead of double power. Indiarubber is
rotted and destroyed by it in a few minutes—a sort of combustion or
quick oxydation taking place—and it is, of course, dangerous to the
softer parts of the human body, such as the air passages and lungs and
the eyes—when present in more than a minimal proportion. I believe that
no one has yet determined exactly how great a percentage of ozone can be
tolerated by a human being in the air taken into the lungs. In ordinary
fresh country or sea-coast air only one part by measure in 700,000 has
been found to be ozone, that is, 1/7000 per cent. But it is quite likely
that much more is occasionally present, since it is very difficult to
arrange a satisfactory examination of the air of any locality so as to
determine how much ozone it contains. It is said that at higher levels
the atmosphere contains more ozone than it does at lower levels.
Public-domain text, read in full here on John Shaqi.
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