Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
Sugar affords a very interesting example of dissociation, commencing
far below the boiling-point, and going on gradually and visibly, with
increasing rapidity as the temperature is raised. Put some white sugar
into a spoon, and heat the spoon gradually over the smokeless gas-flame
or spirit-lamp. At first the sugar melts, then becomes yellow (barley
sugar); this color deepens to orange, then red, then chestnut-brown,
then dark brown, then nearly black (caramel), then quite black, and
finally it becomes a mere cinder. Sugar is composed of carbon and
water; the heat dissociates this compound, separates the water,
which passes off as vapor, and leaves the carbon behind. The gradual
deepening of the color indicates the gradual carbonization, which is
completed when only the dry insoluble cinder remains. An appearance of
boiling is seen, but this is the boiling of the dissociated water, not
of the sugar.
The dissociation temperature of water is far above its boiling-point.
It is 5072° Fahr., under conditions corresponding to those which
make its boiling-point 212°. If we examine the variations of the
boiling-point of water, as the atmospheric pressure on its surface
varies, some curious results follow. To do this the reader must endure
some figures. They are extremely simple, and perfectly intelligible,
but demand just a little attention.
Following are three columns of figures. The first represents
atmospheres of pressure—_i.e._, taking our atmospheric pressure when
it supports 30 inches of mercury in the barometer tube as a unit, that
pressure is doubled, trebled, etc., up to twenty times in the first
column. The second column states the temperature at which water boils
when under the different pressures thus indicated. The third column,
which is the subject for special study just now, shows how much we
must rise the temperature of the water in order to make it boil as we
go on adding atmospheres of pressure; or, in other words, the increase
of temperature due to each increase of one atmosphere of pressure. The
figures are founded on the experiments of Regnault.
Public-domain text, read in full here on John Shaqi.
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