Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
Pressure in Temperature, F. Rise of Temperature
Atmospheres ° for each additional
Atmosphere
1 212
2 249·5 37·5
3 273·3 23·8
4 291·2 17·9
5 306·0 14·8
6 318·2 12·2
7 329·6 11·4
8 339·5 9·9
9 348·4 8·9
10 356·6 8·2
11 364·2 7·6
12 371·1 6·9
13 377·8 6·7
14 384·0 6·2
15 390·0 6·0
16 395·4 5·4
17 400·8 5·4
18 405·9 5·1
19 410·8 4·9
20 415·4 4·6
It may be seen from the above that, with the exception of one
irregularity, there is a continual diminution of the additional
temperature which is required to overcome an additional atmosphere of
pressure, and if this goes on as the pressure and temperatures advance,
we may ultimately reach a curious condition—a temperature at which
additional pressure will demand no additional temperature to maintain
the gaseous state; or, in other words, a temperature may be reached at
which no amount of pressure can condense steam into water, or at which
the gaseous and liquid states merge or become indifferent.
But we must not push this mere numerical reasoning too far, seeing
that it is quite possible to be continually approaching a given point,
without ever reaching it, as when we go on continually halving the
remaining distance. The figures in the above do not appear to follow
according to such a law—nor, indeed, any other regularity. This
probably arises from experimental error, as there are discrepancies
in the results of different investigators. They all agree, however,
in the broad fact of the gradation above stated. Dulong and Arago,
who directed the experiments of the French Government Commission for
investigating this subject, state the pressure at 20 atmospheres to
be 418·4, at 21 = 422·9, at 22 = 427·3, at 23 = 431·4, and at 24
atmospheres, their highest _experimental_ limit, 435·5, thus reducing
the rise of temperature between the 23d and 24th atmospheres to 4·1.
Public-domain text, read in full here on John Shaqi.
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