Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
Having thus stated the facts in popular outline, I shall conclude the
subject by indulging in some speculations of my own on the philosophy
of these general facts or natural laws, and on some of their possible
consequences.
As already stated, the conversion of water into steam under ordinary
atmospheric pressure demands 966·6° of heat over and above that which
does the work of raising the water to 212°, or, otherwise stated, as
much heat is at work in a given weight of steam at 212°, as would raise
the same quantity of water to 1178·6° if it remained liquid.
James Watt concluded from his experiments that a given weight of
steam, whatever may be its density, or, in other words, under whatever
pressure it may exist, contains the same quantity of heat. According
to this, if we reduced the pressure sufficiently to bring down the
boiling-point to 112°, instead of 212°, the latent heat of the steam
thus formed would be 1066·6° instead of 966·6°, or if, on the other
hand, we placed it under sufficient pressure to raise the boiling-point
to 312°, the latent heat of the steam would be reduced to 866·6°,
_i.e._, only 866·6° more would be required to convert the water into
steam. If the boiling-point were 412°, as it is between 19 and 20
atmospheres of pressure, only 766·6° more heat would be required, and
so on, till we reached a pressure which raised the boiling-point to
1178·6°; the water would then become steam without further heating,
_i.e._, the critical point would be reached, and thus, if Watt is
right, we can easily determine, theoretically, the critical temperature
of water.[36]
Mr. Perkins, who made some remarkable experiments upon very high
pressure steam many years ago, and exhibited a steam gun at the
Adelaide Gallery, stated that red-hot water does not boil; that if the
generator be sufficiently strong to stand a pressure of 60,000 lbs.
load on the safety-valve, the water may be made to exert a pressure of
56,000 lbs. on the square inch at a cherry-red heat without boiling.
He made a number of rather dangerous experiments in thus raising water
to a red-heat, and his assertion that red-hot water does not boil is
curious when viewed in connection with Dr. Andrews’ experiments.
I cannot tell how he arrived at this conclusion, having been unable
to obtain the original record of his experiments, and only quote the
above second hand. It is worthy of remark that the temperature he names
is about 1170°, or that which, if Watt is right, must be the critical
temperature of the water. Perkins’ red-hot water would not boil, being
then in the intermediate condition.
So far, we have a nice little theory, which not only shows how
the critical state of water must be reached, but also its precise
temperature; but all this is based on the assumption that Watt made no
mistake.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account