Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
If we could go on heating water in a transparent vessel until
this difference became a vanishing quantity, we should probably
recognize a visible physical change coincident with this cessation of
condensibility by pressure; but this is not possible, as glass would
become red-hot and softened, and thus incapable of bearing the great
pressure demanded. Besides this, glass is soluble in water at these
high temperatures.
If, however, we can find some liquid with a lower boiling-point, we may
go on piling atmosphere upon atmosphere of elastic expansive pressure,
as the temperature is raised, without reaching an unmanageable degree
of heat. Liquid carbonic acid, which, under a single atmosphere of
pressure, boils at 112° below the zero of our thermometer, may thus be
raised to a temperature having the same relation to its boiling-point
that a red-heat has to that of water, and may be still confined within
a glass vessel, provided the walls of the vessel are sufficiently thick
to bear the strain of the elastic outstriving pressure. In spite of its
brittleness glass is capable of bearing an enormous strain _steadily
applied_, as may be proved by trying to break even a mere thread of
glass by direct pull.
Dr. Andrews thus treated carbonic acid, and the experiment, as I have
witnessed its repetition, is very curious. A liquid occupies the lower
part of a very strong glass tube, which appears empty above. But this
apparent void is occupied by invisible carbonic acid gas, evolved by
the previous boiling of the liquid carbonic acid below. We start at
a low temperature—say 40° Fahr. Then the temperature is raised; the
liquid boils until it has given off sufficient gas or vapor to exert
the full expansive pressure or tension due to that temperature. This
pressure stops the boiling, and again the surface of the liquid is
becalmed.
This is repeated at a higher temperature, and thus continued until we
approach nearly to 88° Fahr., when the surface of the liquid loses
some of its sharp outline. Then 88° is reached, and the boundary
between liquid and gas vanishes; liquid and gas have blended into one
mysterious intermediate fluid; an indefinite fluctuating something
is there filling the whole of the tube—an etherealized liquid or a
visible gas. Hold a red-hot poker between your eye and the light; you
will see an upflowing wavy movement of what appears like liquid air.
The appearance of the hybrid fluid in the tube resembles this, but is
sensibly denser, and evidently stands between the liquid and gaseous
states of matter, as pitch or treacle stands between solid and liquid.
The temperature at which this occurs has been named by Dr. Andrews
the “_critical temperature_”; here the gaseous and liquid states are
“_continuous_,” and it is probable that all other substances capable of
existing in both states have their own particular critical temperatures.
Public-domain text, read in full here on John Shaqi.
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