Science in Short ChaptersWilliams, W. Mattieu (William Mattieu)
Science
Science in Short Chapters
Williams, W. Mattieu (William Mattieu)
Science
By connecting the mercury cup with one terminal of the battery, and the
upper platinum-wire with the other, a brilliant and perfectly steady
light was produced, not so intense as the ordinary disruption arc
between carbons, but equally if not more effective, on account of the
magnitude of brilliant radiating surface.
Some curious phenomena accompanied this illumination of the carbon. The
mercury column fell to about half its barometric height, and presently
the glass opposite the carbon stick became slightly dimmed by the
deposition of a thin film of sooty deposit.
At first the depression of the mercury was attributed to the formation
of mercurial vapor, and is described accordingly in the specification;
but further observation refuted this theory, for no return of the
mercury took place when the tube was cooled. The depression was
permanent. The formation of vaporous carbon was suggested by one of the
capitalists; but neither Mr. Starr nor myself was satisfied with this,
nor with any other surmise we were able to make during Mr. Starr’s
lifetime, nor up to the period of final abandonment of the enterprise.
When this occurred the remaining apparatus was assigned to me, and I
retained possession of the finally arranged tube and carbon for many
years, and have shown it in action worked by a small Grove’s battery
in the Town Hall of Birmingham, and many times to my pupils at the
Birmingham and Midland Institute.
These exhibitions suggested an explanation of the mysterious gaseous
matter, which I believe to be the correct one, and also of the carbon
deposit. It is this:—That the carbon contains occluded oxygen; that
when the carbon is heated some of this oxygen combines with the
carbon, forming carbonic oxide and carbonic acid, and a little smoke.
I proved the presence of carbonic acid by the usual tests, but did not
quantitatively determine its proportion of the total atmosphere.
If I were fitting up another tube on this principle I should wash it
with a strong solution of caustic potash before filling with mercury,
and allow some of the potash solution to float on the mercury surface,
by filling the tube while the glass remained moistened with the
solution. My object would be to get rid of the carbonic acid as soon as
formed, as the observations I have made lead me to believe that—when
the carbon stick is incandescent in an atmosphere of carbonic acid or
carbonic oxide—a certain degree of dissociation and re-combination is
continually occurring, which weakens and would ultimately break up the
carbon stick, and increases the sooty deposit.
The large battery was arranged for intensity, but even then it was
found that the quantity (I use the old-fashioned terms) of electricity
was excessive, and that it worked more advantageously when the cells
were but partially filled with acid and sulphate. A larger stick of
carbon might have been used with the whole surface in full action.
Public-domain text, read in full here on John Shaqi.
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