Scientific American, September 29, 1883 Supplement. No. 404Various
Science
Scientific American, September 29, 1883 Supplement. No. 404
Various
Science -- Periodicals
1. In many districts copper and tin ores are found near together (as
in Cornwall), so that under these circumstances bronze could have been
obtained by smelting both at once, and together.
2. In olden times only the upper horizon of copper deposits were worked
in all districts. In these, as we know, the ores are mostly oxides
(with native copper). Such ores are easily worked and yield largely.
3. In regard to the mixing of metals, the metallurgists everywhere must
have soon learned by experience that the metal remained soft and red
when too little tin was added, while too much tin made it light colored
and lustrous, but, at the same time, very brittle. Hence, we find that
among all peoples the alloys used for weapons contain from 6 to 16, or,
more closely, 8 to 12 per cent. of tin. These mixtures have been found
to do the best.
4. Bronzes, as we shall see below, by slight admixtures and certain
treatment, can be made so tough and hard that they will compare with
moderately hard steel.
So we see: The metal was useful, and there was an excess of rich and
easily worked ores. Under such conditions, of course, the age of bronze
would flourish a long time.
Zinc ores frequently occur on copper beds, and yet zinc is rarely found
in quantity worth mentioning in the bronzes of the ancients. There are
two reasons for this:
1. Near the surface of the earth zinc occurs as calamine (silicate of
zinc), which is a gray, unattractive, earthy looking mineral, not heavy
enough to be taken for a metallic ore, and would naturally be thrown
away and not put in the furnace.
2. If some zinc ore did get into the furnace, part of it would be
volatilized and part oxidized by subsequent smelting.
In later times, however, we find zinc ores used a good deal. We can
distinguish three types of zinc alloys:
1. Copper with 10 to 20 per cent. zinc produces a red metal, red brass,
which is similar to bronze that is poor in tin.
2. Copper with 20 or 30 (and even 40) per cent. of zinc, gives a yellow
metal (yellow or ordinary brass), which has more of a golden color than
bronze with much tin, but quite brittle.
3. Statuary metal, which is made of copper with quite a good deal of
zinc and little tin (often lead) can be called brass containing tin.
All three types may be used for casting (ornaments, statues, and
coin), but are not useful for tools or weapons, because they have not
sufficient strength.
After discussing the natural association of ores, and the most
important alloys of copper, we will turn to the analyses of antique
alloys. I have found it necessary to divide them into two groups:
1. Alloys from which the weapons and tools were _forged_. These are
pure and genuine bronzes. I shall designate them as malleable metals or
weapon bronzes.
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