Scientific American Supplement, No. 1082, September 26, 1896Various
Science
Scientific American Supplement, No. 1082, September 26, 1896
Various
Science -- Periodicals
My experiments on the liquefaction of helium were carried out with a
sample of that gas, sent to me by Prof. Ramsay from London, in a
sealed glass tube holding about 140 c. cm. I take this opportunity of
rendering him my most sincere thanks. In his letter Prof. Ramsay
informed me that the gas had been obtained from the mineral clevite,
and that it was quite free from nitrogen and other impurities, which
could be removed by circulation over red hot magnesium, oxide of
copper, soda lime, and pentoxide of phosphorus. The density of the gas
was 2.133 and the ratio of its specific heats (Cp/Cv) 1.652, the
latter figure indicating that the molecule of helium was monatomic, as
had already been found to be the case with argon. Prof. Ramsay further
informed me that the gas was only very slightly soluble in water, 100
c. cm. of water dissolving scarcely 0.7 c. cm. of helium.
From the results of my earlier experiments I had been led to expect
that it would be only possible to liquefy helium at a very low
temperature; the small values obtained for the density and solubility
of the gas, together with the fact that its molecule is monatomic,
indicating a very low boiling point. For this reason I did not
consider it necessary to use liquid ethylene as a preliminary cooling
agent, but proceeded directly to conduct my experiments at the lowest
temperature that could be produced by means of liquid air. The
apparatus employed in these investigations is figured in the
accompanying diagram.
The helium was contained in the glass tube, c, of the Cailletet's
apparatus, C. The tube, c, reached to the bottom of a glass vessel, a,
which was intended to contain the liquid air. The vessel, a, was
surrounded by three glass cylinders, b, b' and b", closed at the
bottom and separated from one another. The outer vessel, b", was made
just large enough to fit into the brass collar, o, which supported the
lid, u, of the apparatus. The tube, a, fitted into an opening in the
center of the lid; the tube, t, connected with an apparatus delivering
liquid oxygen, passed through a hole on the right. The vessel, b, was
also connected with a mercury manometer and air pump by means of a T
tube, p, v, one arm of which passed through the third hole in the lid
of the apparatus. The tube, a, was closed by a stopper, through which
passed the tube, c, of the Cailletet's apparatus, a tube connected
with the drying apparatus, u, u', and one limb of a T tube, by means
of which the manometer and air pump could be put in connection with
the interior of the vessel. The lower part of the whole apparatus was
inclosed in a thick walled vessel, e, containing a layer of phosphorus
pentoxide.
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