Scientific American Supplement, No. 1082, September 26, 1896Various
Science
Scientific American Supplement, No. 1082, September 26, 1896
Various
Science -- Periodicals
By turning the valve, k, the vessel, b, could be partially filled with
liquid oxygen, which, under a pressure of 10 mm. of mercury, boiled at
about -210° C. Almost immediately the gaseous air began to condense
and collect in the tube, a; a supply of fresh air was constantly
maintained through the drying tubes, u and u', which were filled with
sulphuric acid and soda lime respectively. When the quantity of liquid
air ceased to increase, the tap on the U tube, u, was closed, the T
tube, p' v', was connected with the manometer and air pump, and the
liquid air was made to boil under a pressure of 10 mm. of mercury. In
order to protect the liquid air from its warmer surroundings, a very
thin, double wall tube, f, reaching to the level of the liquid in the
outer vessel, was placed inside the tube, a. When, as in some of my
experiments, liquid oxygen was used in the inner vessel, this part of
the apparatus was dispensed with.
[Illustration: Helium cooling apparatus]
Using the apparatus I have just described, I carried out two series of
experiments, in which liquid air and liquid oxygen were employed as
cooling agents. The tube of the Cailletet's apparatus was thoroughly
exhausted by means of a mercury pump, and then carefully filled with
dry helium. In the first series of experiments the helium, confined
under a pressure of 125 atmospheres, was cooled to the temperature of
oxygen boiling, first under atmospheric pressure (-182.5°), and then
under a pressure of 10 mm. of mercury (-210°). The helium did not
condense under these conditions, and even when, as in subsequent
experiments, I expanded the gas till the pressure fell to twenty
atmospheres, and in some cases to one atmosphere, I could not detect
the slightest indication that liquefaction had taken place. The first
time that I compressed the gas I had, indeed, noticed that a small
quantity of a white substance separated out and remained at the bottom
of the tube when the pressure was released. Possibly this may have
been due to the presence of a small trace of impurity in the helium,
but it could not have constituted more than 1 per cent. of the total
volume of the gas.
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