Scientific American Supplement, No. 275, April 9, 1881Various
Science
Scientific American Supplement, No. 275, April 9, 1881
Various
Science -- Periodicals
Dr. Dupré asked Dr. Debus how it was that a molecule of pentathionate could
be re-crystallized, whereas two molecules of pentathionate, which should,
when half decomposed, furnish a molecule of tetra and a molecule of
pentathionate, could not.
Dr. Armstrong then read a _"Preliminary Note on some Hydrocarbons from
Rosin Spirit."_ After giving an account of our knowledge of rosin spirit,
the author described the result of the examination of the mixture of
hydrocarbons remaining after heating it with sulphuric acid and diluting
with half its volume of water and steam distilling. Thus treated rosin
spirit furnishes about one-fourth of its volume of a colorless mobile
liquid, which after long-continued fractional distillation is resolved into
a variety of fractions boiling at temperatures from 95° to over 180°. Each
of the fractions was treated with concentrated sulphuric acid, and the
undissolved portions were then re-fractionated. The hydrocarbons dissolved
by the acid were recovered by heating under pressure with hydrochloric
acid. Besides a cymene and a toluene, which have already been shown to
exist in rosin spirit, metaxylene was found to be present. The hydrocarbons
insoluble in sulphuric acid are, apparently, all members of the C_nH_{2n}
series; they are not, however, true homologues of ethylene, but hexhydrides
of hydrocarbons of the benzene series. Hexhydro-toluene and probably
hex-hydrometaxylene are present besides the hydrocarbon, C_10H_20, but it
is doubtful if an intermediate term is also present. It is by no means
improbable, however, that these hydrocarbons are, at least in part,
products of the action of the sulphuric acid. Cahours and Kraemer's and
Godzki's observations on the higher fractions of crude wood spirit, in
fact, furnish a precedent for this view. Referring to the results obtained
by Anderson, Tilden, and Renard, the author suggests that rosin spirit
perhaps contains hydrides intermediate in composition between those of
the C_nH_{2n-6} and C_nH_{2n} series, also derived like the latter from
hydrocarbons of the benzene series. Finally, Dr Armstrong mentioned that
the volatile portion of the distillate from the non-volatile product of the
oxidation of oil of turpentine in moist air furnishes ordinary cymene when
treated in the manner above described. The fact that rosin spirit yields a
different cymene is, he considers, an argument against the view which
has more than once been put forward, that rosin is directly derived from
terpene. Probably resin and turpentine, though genetically related, are
products of distinct processes.
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