Scientific American Supplement, No. 275, April 9, 1881Various
Science
Scientific American Supplement, No. 275, April 9, 1881
Various
Science -- Periodicals
The next paper was _"On the Determination of the Relative Weight of Single
Molecules,"_ by E. Vogel, of San Francisco. This paper, which was taken as
read, consists of a lengthy theoretical disquisition, in which the author
maintains the following propositions: That the combining weights of all
elements are one third of their present values; the assumption that equal
volumes of gases contain equal numbers of molecules does not hold good;
that the present theory of valency is not supported by chemical facts, and
that its elimination would be no small gain for chemistry in freeing it
of an element full of mystery, uncertainty, and complication; that the
distinction between atoms and molecules will no longer be necessary;
that the facts of specific heat do not lend any support to the theory of
valency. The paper concludes as follows: "The cause of chemical action is
undoubtedly atmospheric pressure, which under ordinary conditions is equal
to the weight of 76 cubic centimeters of mercury, one of which equals 6.145
mercury molecules, so that the whole pressure equals 467 mercury molecules.
This force--which with regard to its chemical effect on molecules can be
multiplied by means of heat--is amply sufficient to bring about the highest
degree of molecular specific gravity by the reduction of the molecular
volumes. To it all molecules are exposed and subjected unalterably, and
if not accepted as the cause of chemical action, its influence has to be
eliminated to allow the introduction and display of other forces."
The next communication was _"On the Synthetical Production of Ammonia,
by the Combination of Hydrogen and Nitrogen in Presence of Heated Spongy
Platinum (Preliminary Notice),"_ by G. S. Johnson. Some experiments, in
which pure nitrogen was passed over heated copper containing occluded
hydrogen, suggested to the author the possibility of the formation of
ammonia; only minute traces were formed. On passing, however, a mixture of
pure nitrogen (from ammonium nitrite) and hydrogen over spongy platinum at
a low red heat, abundant evidence was obtained of the synthesis of ammonia.
The gases were passed, before entering the tube containing the platinum,
through a potash bulb containing Nessler reagent, which remained colorless.
On the contrary, the gas issuing from the platinum rapidly turned Nessler
reagent brown, and in a few minutes turned faintly acid litmus solution
blue; the odor of NH_3 was also perceptible. In one experiment 0.0144
gramme of ammonia was formed in two hours and a half. The author promises
further experiment as to the effect of temperature, rate of the gaseous
current, and substitution of palladium for platinum. The author synthesized
some ammonia before the Society with complete success.
The President referred to the synthesis of ammonia from its elements
recently effected by Donkin, and remarked that apparently the ammonia was
formed in much larger quantities by the process proposed by the author of
the present paper.
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