Scientific American Supplement, No. 288, July 9, 1881 — John Shaqi
Scientific American Supplement, No. 288, July 9, 1881Various
Science
Scientific American Supplement, No. 288, July 9, 1881
Various
Science -- Periodicals
What happens in chemical experiment may be developed on a large scale in
burning grocery, drug, or drysalters' stores, when great quantities of
materials, such as just mentioned, including common salt, almost always
present, are heated most intensely, and then subjected to the action of
water in heavy dashes, or in form of spray or steam.
Picric acid, the nature of which we have several times previously
mentioned, and which explodes at 600° F. (only 28° above gunpowder), may
also be an element in such explosions during fires. Its salts form, in
combinations, various powerful explosives, much exceeding gunpowder
in force; and they have been used to a considerable extent in Europe.
Picric acid, now much employed by manufacturers and dyers for obtaining
a yellow color, is always kept in store largely by drysalters and
druggists, and generally by dyers, but in smaller quantity.
In a very destructive fire which occurred in Liverpool, Eng., in
October, 1874, involving the loss of several "fire-proof" stores,
repeated explosions of the vapor of turpentine rent ponderous brick
arched vaults, and exposed to the flames stocks of cotton, etc., in the
stories above. This conflagration was started by the carelessness of an
_employee_ in snuffing a tallow candle with his fingers and throwing the
burning snuff into the open bung-hole of a sample barrel of turpentine,
of which liquid there were many hundreds of barrels on storage in the
buildings. Turpentine vapor united with chlorine gas may not produce
explosion, but by spreading flames almost instantly throughout the
burning buildings, such burnings have practically equaled, if not
excelled, explosions, which may sometimes be fire-extinguishers. In such
cases detonation may be prevented by there being ample space to receive
the suddenly ignited vapor, lessening the tension of it, but carrying
the flames much more rapidly than otherwise to inflammable materials at
great distance.
If disastrous results have arisen from the vapor of turpentine as a fire
spreader in vaults without windows, it is possible that if a quantity of
hot water were suddenly converted into steam in closely confined spaces,
effects of pressure might be observed, less destructive perhaps, but
resembling those which other explosives might produce. If the immense
temperature attained in some conflagrations be considered--sufficient
to melt iron and vitrify brick--it is possible to conceive of water as
being instantly converted into steam. Even a very small quantity of
water thus expanded could produce most disastrous results. While such
formation of steam, if it happened, would certainly extinguish most
flames in direct contact, the general phenomena shown would be
explosive.
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