Scientific American Supplement, No. 288, July 9, 1881Various
Science
Scientific American Supplement, No. 288, July 9, 1881
Various
Science -- Periodicals
By referring to the table of combining weights given in a previous
paper, it will be seen that 100 parts of calcium carbonate will yield 44
parts of carbonic acid. Instead of hydrochloric acid any other acid may
be used, and in the practical manufacture of carbonic acid for aerated
waters sulphuric acid is the one usually employed. Carbonic acid is
colorless and inodorous, but has a peculiar sharp taste; it is half as
heavy again as air, its exact specific gravity being 1529; one hundred
cubic inches weigh 47.26 grains. It is uninflammable, and does not
support combustion or animal respiration. Under a pressure of about 38
atmospheres, at a temperature of 32° F., carbonic acid condenses into
a colorless liquid, which may also be frozen into a compact mass
resembling ice, or into a white powder like snow. Carbonic acid is
soluble in water, and at the ordinary pressure and temperature one
volume of water will hold in solution one volume of the gas; under
increased pressures, far larger quantities of the gas can be held in
solution, but this is rapidly evolved as soon as the excess of pressure
is removed. Upon this property the manufacture of aerated waters
depends. The presence of free carbonic acid can be easily detected by
causing the gas to pass over the surface of some clear lime-water. If
any be present a white film of carbonate of lime will at once be formed.
In testing carbonic acid in a state of combination, the gas must first
be liberated by acting upon the substance with a stronger acid, and
then applying the lime-water test. The presence of large quantities of
carbonic acid in a gaseous mixture can be readily detected by plunging
into the vessel a lighted taper, which will be immediately extinguished.
This ought always to be adopted in a brewery, where many fatal accidents
have happened through workmen going down into empty fermenting vats and
wells without first taking this precaution.
The presence of carbon in this colorless gas can be demonstrated by
causing some of it to pass over a piece of the metal potassium placed
in a hard glass tube, and heated to dull redness; the potassium then
eagerly combines with the oxygen, forming oxide of potassium, and the
carbon is liberated and can be separated in the form of a black powder
by washing the tube out with water.
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