Scientific American Supplement, No. 288, July 9, 1881Various
Science
Scientific American Supplement, No. 288, July 9, 1881
Various
Science -- Periodicals
is exceedingly superficial, the ashes being simply tested for their
_alkaline_ strength, with no discrimination between potash and soda,
which is a difficult and delicate chemical test. Soda being now far
cheaper than potash, and also the alkaline equivalent, as previously
explained, being greatly in favor of soda, there has been every
inducement to "enterprising" producers of ashes to adulterate them with
soda, which, in many cases, has been largely done. Another source of
potash has been beetroot ashes, very similar to wood ashes, and also
German carbonate of potash, which latter about corresponds to a common
soda ash, as compared with caustic soda; with these articles, a tedious
boiling process, very similar to the old process for the production
of hard soap, had to be adopted, the ashes, or carbonate of potash,
previously being dissolved and causticized with lime by the soap maker.
The production of a first-class soft soap was also a very difficult
operation, as the impurities and soda contained varied considerably,
often causing the "boil" to go wrong and give considerable trouble to
the soapboiler.
During the last two years, however, caustic potash has been introduced,
that manufactured by the Greenbank Alkali Co., of St. Helens, being very
nearly pure. With this article there is no difficulty in producing a
pure potash soap, either for wool scouring, fulling, or sizing, by a
cold process very similar to that described for the production of hard
soda soap with pure powdered caustic soda.
The following directions will produce an excellent soap for wool
scouring: Fifty pounds of Greenbank pure caustic potash are put into
eight gallons of soft water; the potash dissolves immediately, heating
the water. This lye is allowed to cool, and then slowly added, with
continual mixing, to 20 gallons of cotton seed oil, mixed with 20 pounds
of melted tallow, the whole being brought to a temperature of about 90°
F. After stirring for some minutes, so as to completely combine the lye
and oil, the mixture is left for two days in a warm place, when a slow
and gradual saponification of the mass takes place. If when examined the
oil and lye are then found not completely combined, the stiff soap is
again stirred and left two days, when the saponification will be found
complete, the result being the formation of about 330 pounds of very
stiff potash soap, each pound being equal to about two pounds of the
ordinary "fig" soap sold. The requisite quantity is thrown into the
scouring vat with about five per cent of its weight of refined pearl ash
to increase the alkali present, the weight depending somewhat upon the
kind of wool washed on purpose for which the soap is required. If the
wool is very dirty or greasy, rather a stronger soap is sometimes
advisable. This can easily be attained by reducing the quantity of oil
used to 18 gallons.
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