Scientific American Supplement, No. 299, September 24, 1881Various
Science
Scientific American Supplement, No. 299, September 24, 1881
Various
Science -- Periodicals
I have always held that to boil gelatine is to spoil it, and, even when
emulsification is made with a few grains to the ounce and cooled down
before adding the bulk, the damage is done to the smaller quantity,
so that when mixed it contaminates the whole mass; moreover, it is
impossible to set and wash the gelatine without the aid of ice.
I have lately made several batches (with the thermometer at 92° in the
shade, and the washing water at 78°) as follows:
Hard gelatine...............,...... ½ ounce.
Water.............................. 2 ounces.
Alcohol............................ 2 "
Bromide ammonia....................150 grains.
Liquor ammonia, 880................ 60 drops.
When all is thoroughly dissolved and of about 120° temperature, add,
stirring all the time,
Nitrate silver..................... 60 grains,
Water.............................. ¾ ounce.
Alcohol............................ ¾ "
Then again add,
Nitrate silver.....................140 grains.
Water.............................. 1 ounce.
Alcohol............................ 1 "
Both solutions being warmed to about 120°.
My object is adding the silver in two quantities will be obvious to
many--viz., when the first portion of silver is mixed, nitrate of
ammonia is liberated (which is a powerful restrainer), and the bulk of
the solution being increased, the remainder of the silver may be added
in a much more concentrated state.
The alcohol, both in the gelatine and silver solutions, plays a most
important part: (1) It prevents decomposition of the gelatine. (2) It
allows the gelatine to be precipitated with a much smaller quantity of
alcohol (say about 10 ounces).
After letting the emulsion stand for a few minutes to ripen, I pour in
slowly about eight ounces of alcohol, stirring all the time, and keeping
the emulsion warm; the emulsion will adhere to the stirring-rod and the
bottom of the vessel in a soft mass, and all that is now required is to
pour away the alcohol, allow the emulsion to cool, tear it into small
pieces, wash in several changes of cold water, make up the quantity to
ten ounces, and strain; it is then ready for coating.
By this formula I have no difficulties whatever; my plates set in about
five minutes, and their quality is such that, "unless a better method is
devised," I intend to adopt it in all weathers.
One word more as to the alcohol. It will prevent the decomposition of
gelatine when boiling goes on, or when in the presence of foreign salts;
no flocculent deposit is noticed in the alcohol after the emulsion has
been precipitated.--_Photographic News_.
* * * * *
THE DISTILLATION AND RECTIFICATION OF ALCOHOLS BY THE RATIONAL USE OF
LOW TEMPERATURES.
By RAOUL PICTET.
Public-domain text, read in full here on John Shaqi.
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