Scientific American Supplement, No. 299, September 24, 1881 — John Shaqi
Scientific American Supplement, No. 299, September 24, 1881Various
Science
Scientific American Supplement, No. 299, September 24, 1881
Various
Science -- Periodicals
It results from all the laws that we have cited that by properly
regulating the tensions of the vapors of a mixture of alcohol and water,
and the temperature of the liquid, we shall be able to obtain a liquid
of a desired richness by the condensation of these vapors.
III. It was likewise indispensable to make sure of one important fact:
When the temperature of a liquid like alcohol is considerably lowered,
can the distillation of a given weight of this substance be effected
with sufficient rapidity for industrial requirements? Repeated
experiments with a host of volatile liquids have demonstrated the
following laws:
If we introduce a volatile liquid into two spherical receivers connected
by a wide tube, and if these be kept at different temperatures after
driving out all the air from the apparatus, the liquid distills from the
warmer into the cooler receiver, and we ascertain that:
h. The weight of the liquid which distills in the unit of time increases
with the deviation of temperature between the two receivers.
i. The weight of the liquid which distills in the unit of time is
constant for a same deviation of temperature between the receivers,
whatever be, moreover, the absolute temperature of the receivers.
k. The weight of the liquid distilled in the unit of time is
proportional to the active surfaces of the receivers; that is to say,
to the surfaces which are the seat of passage of heat through their
thickness.
l. The least trace of a foreign gas in the vapors left in the apparatus
throws the preceding laws into confusion, and checks distillation to a
considerable degree, especially at low temperatures.
Thus, water distilling between 100° and 60° will pass over as quickly
as that which is distilling between 40° and 0°. Absolute temperature is
without influence, provided every trace of air or foreign gas be got rid
of.
The distillatory apparatus should be provided with an excellent
air-pump, capable of preventing all those entrances of air which are
inevitable in practice.
The following is the industrial application that we have endeavored to
make of these theoretical views: The rectification of alcohols is one
of the most complex of operations; it looks toward several results
simultaneously. Alcohol derived from the fermentation of grain, sugar,
and of all starchy matters in general, contains an innumerable host of
different products, which may be grouped under four principal heads:
1. Empyreumatic essential oils, characteristic of the source of the
alcohol, and having a powerful odor which infects the total mass of
the crude spirits. 2. A considerable quantity of water. 3. A certain
quantity of pure alcohol. 4. A variable proportion of volatile
substances, composed in great part of ethers, different alcohols, and
bodies as yet not well defined. These latter affect the quality of
the alcohol by an odor which is entirely different from that of the
essential oils.
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