Scientific American Supplement, No. 344, August 5, 1882Various
Science
Scientific American Supplement, No. 344, August 5, 1882
Various
Science -- Periodicals
Iron, as you all know, is known to the arts in three forms: cast or
crude, steel, and wrought or malleable. Cast iron varies much in
chemical composition, being a mixture of iron and carbon chiefly, as
constant factors, with which silicium in small quantities (from 1 to
5 per cent.), phosphorus, sulphur, and sometimes manganese (e.g.
spiegeleisen) and various other elements are combined. All of these have
some effect upon the crystalline structure of the mass, but whatever
crystallization takes place occurs at the moment of solidification, or
between that and a red heat, and varies much, according to the time
occupied in cooling, as to its composition. My own experience leads me
to think that a cast iron having about 3 per cent. of carbon, a small
per centage of phosphorus, say about ½ of 1 per cent., and very small
quantities of silicium, the less the better, and traces of manganese
(the two latter substances _slagging_ out almost entirely during the
process of remelting for casting), makes a metal best adapted to the
general use of the founder. Such proportions will make a soft, even
grained, dark gray iron, whose crystals are small and bright, and whose
fracture will be uneven and sharp to the touch. The phosphorus in this
instance gives the metal liquidity at a low temperature, but does not
seem to influence the crystallization to any appreciable extent. The two
elements to be avoided by the founder are silicium and sulphur. These
give to iron a peculiar crystalline appearance easily recognized by
an experienced person. Silicium seems to obliterate the sparkling
brilliancy of the crystalline faces of good iron, and replace them with
very fine dull ones only discernible with a lens, and the iron breaks
more like stoneware than metal, while sulphur in appreciable quantities
gives a striated crystalline texture similar to chilled iron, and very
brittle. Phosphorus in very large quantities acts similarly. The form of
the crystal in cast iron is the octahedron, so that right angles with
sharp corners should be avoided as much as possible in castings, as the
most likely position for a crystal to take would be with its faces along
the line of the angle. Steel, to be of any value as such, _must_ be made
of the purest material. Phosphorus and sulphur _must_ not exist, except
in the most minute quantities, or the metal is worthless. If either of
these substances be present in a bar of steel, its structure will
be coarse, crystalline and weak. The reason of this is unknown, but
probably their presence reduces the power of cohesion; and, that being
reduced, gives the molecules of steel greater freedom to arrange
themselves in conformity with their polarity, and this in its turn again
weakens the mass by the tendency of the crystals to cleavage in certain
directions. Carbon is a constant element in steel, as it is in cast
iron, but is frequently replaced by chromium, titanium, etc., or is said
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